Chemical vapor deposition condition dependence of reconstructed surfaces on 4H-SiC (0001), (0001), and (1100) surfaces

Kenta Chokawa, Emi Makino, Norikazu Hosokawa, Shoichi Onda, Yoshihiro Kangawa, Kenji Shiraishi

研究成果: ジャーナルへの寄稿学術誌査読

3 被引用数 (Scopus)

抄録

Chemical vapor deposition has been developed to enable defect-free 4H-SiC crystals to be grown at lower cost and with higher growth rates. However, the structure and stability of 4H-SiC surfaces during crystal growth has not been clarified. In this study, we performed first-principles calculations and obtained the surface energies of ideal surfaces and Si-terminated surfaces on (0001), (000) and (100) surfaces. For the (0001) and (000) surfaces, the Si-terminated surfaces are more stable than the ideal surfaces and Si atoms are adsorbed onto the surfaces up to high temperatures. The ideal surface on the (100) surface is stable, and the Si-terminated surface changes to an ideal surface at lower temperatures than on the (0001) and (000) surfaces. These results indicate the possible temperature ranges in which to perform crystal growth. Thus, we clarified the conditions required to grow 4H-SiC crystals and the dependency of these structures on surface orientation.

本文言語英語
論文番号115501
ジャーナルJapanese journal of applied physics
58
11
DOI
出版ステータス出版済み - 2019

!!!All Science Journal Classification (ASJC) codes

  • 工学一般
  • 物理学および天文学一般

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