TY - CHAP
T1 - CHAPTER 6
T2 - Manganese Catalysis
AU - Kuninobu, Y.
AU - Sueki, S.
AU - Kaplaneris, N.
AU - Ackermann, L.
N1 - Funding Information:
Y.K. acknowledges JSpS KAKEnHI Grant numbers Jp 17H03016 and 18H04656. S.S. expresses his thanks to support by the Cooperative research program of “network Joint research Center for Materials and devices” and JSpS KAKEnHI Grant numbers Jp 18K05110. Generous support by the dFG (Gottfried-Wilhelm-leibniz-preis), the onassis Foundation (fellowship to n.K.), is gratefully acknowledged.
Publisher Copyright:
© 2021 The Royal Society of Chemistry.
PY - 2021
Y1 - 2021
N2 - In this chapter, we summarize the manganese-catalysed transformations developed over the last 20 years. Because manganese is the third most abundant transition metal according to the Clarke number, the price is cheaper than that of almost any other transition metal. Therefore, the development of synthetic organic reactions using manganese catalysts is highly important and desired. In addition, several reactions, which are specific to manganese catalysts, have also been reported. This chapter describes (1) oxidation reactions (epoxidation of alkenes, C-H oxidation, and dehydrogenation); (2) reduction (of alkenes and heterocycles, alkynes, carbonyl compounds, imine derivatives, nitriles and amides, CO2 and CO, and alcohols); (3) carbon-carbon bond formation (addition to unsaturated molecules and cross-coupling reactions); (4) C-H activation (addition to C-C multiple bonds, substitutive C-H functionalization, C-H alkylation, C-H arylation, C-N bond forming reactions, and domino C-H activation reactions); and (5) others (cyclization, annulation, addition to olefins, coupling reaction, C-C bond cleavage, and various others).
AB - In this chapter, we summarize the manganese-catalysed transformations developed over the last 20 years. Because manganese is the third most abundant transition metal according to the Clarke number, the price is cheaper than that of almost any other transition metal. Therefore, the development of synthetic organic reactions using manganese catalysts is highly important and desired. In addition, several reactions, which are specific to manganese catalysts, have also been reported. This chapter describes (1) oxidation reactions (epoxidation of alkenes, C-H oxidation, and dehydrogenation); (2) reduction (of alkenes and heterocycles, alkynes, carbonyl compounds, imine derivatives, nitriles and amides, CO2 and CO, and alcohols); (3) carbon-carbon bond formation (addition to unsaturated molecules and cross-coupling reactions); (4) C-H activation (addition to C-C multiple bonds, substitutive C-H functionalization, C-H alkylation, C-H arylation, C-N bond forming reactions, and domino C-H activation reactions); and (5) others (cyclization, annulation, addition to olefins, coupling reaction, C-C bond cleavage, and various others).
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U2 - 10.1039/9781788012775-00139
DO - 10.1039/9781788012775-00139
M3 - Chapter
AN - SCOPUS:85095977179
T3 - RSC Catalysis Series
SP - 139
EP - 230
BT - Catalysis with Earth-abundant Elements
A2 - Schneider, Uwe
A2 - Thomas, Stephen
PB - Royal Society of Chemistry
ER -