C–H Arylation of Benzene with Aryl Halides using H2 and a Water-Soluble Rh-Based Electron Storage Catalyst

Takeshi Yatabe; Tamon Tome; Yukina Takahashi; Takahiro Matsumoto; Ki Seok Yoon; Hidetaka Nakai; Seiji Ogo

doi:10.1002/chem.202102735

C–H Arylation of Benzene with Aryl Halides using H₂ and a Water-Soluble Rh-Based Electron Storage Catalyst

Takeshi Yatabe, Tamon Tome, Yukina Takahashi, Takahiro Matsumoto, Ki Seok Yoon, Hidetaka Nakai, Seiji Ogo

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

3 被引用数 (Scopus)

抄録

This paper reports the first example of C−H arylation of benzene under mild conditions, using H₂ as an electron source {turnover numbers (TONs)=0.7–2.0 for 24 h}. The reaction depends on a Rh-based electron storage catalyst, and proceeds at room temperature and in aqueous solution. Furthermore, the H₂ is inactive during the radical transfer step, greatly reducing unwanted side reactions.

本文言語	英語
ページ（範囲）	17326-17330
ページ数	5
ジャーナル	Chemistry - A European Journal
巻	27
号	69
DOI	https://doi.org/10.1002/chem.202102735
出版ステータス	出版済み - 12月 9 2021

!!!All Science Journal Classification (ASJC) codes

触媒
有機化学

文献へのアクセス

10.1002/chem.202102735

他のファイルとリンク

引用スタイル

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title = "C–H Arylation of Benzene with Aryl Halides using H2 and a Water-Soluble Rh-Based Electron Storage Catalyst",

abstract = "This paper reports the first example of C−H arylation of benzene under mild conditions, using H2 as an electron source {turnover numbers (TONs)=0.7–2.0 for 24 h}. The reaction depends on a Rh-based electron storage catalyst, and proceeds at room temperature and in aqueous solution. Furthermore, the H2 is inactive during the radical transfer step, greatly reducing unwanted side reactions.",

keywords = "C−H arylation, H activation, electron storage catalyst",

author = "Takeshi Yatabe and Tamon Tome and Yukina Takahashi and Takahiro Matsumoto and Yoon, {Ki Seok} and Hidetaka Nakai and Seiji Ogo",

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AU - Yatabe, Takeshi

AU - Tome, Tamon

AU - Takahashi, Yukina

AU - Matsumoto, Takahiro

AU - Yoon, Ki Seok

AU - Nakai, Hidetaka

AU - Ogo, Seiji

PY - 2021/12/9

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N2 - This paper reports the first example of C−H arylation of benzene under mild conditions, using H2 as an electron source {turnover numbers (TONs)=0.7–2.0 for 24 h}. The reaction depends on a Rh-based electron storage catalyst, and proceeds at room temperature and in aqueous solution. Furthermore, the H2 is inactive during the radical transfer step, greatly reducing unwanted side reactions.

AB - This paper reports the first example of C−H arylation of benzene under mild conditions, using H2 as an electron source {turnover numbers (TONs)=0.7–2.0 for 24 h}. The reaction depends on a Rh-based electron storage catalyst, and proceeds at room temperature and in aqueous solution. Furthermore, the H2 is inactive during the radical transfer step, greatly reducing unwanted side reactions.

KW - C−H arylation

KW - H activation

KW - electron storage catalyst

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