Catalytic hydrogenation of carboxamides and esters by well-defined Cp*Ru complexes bearing a protic amine ligand

Masato Ito; Takashi Ootsuka; Ryo Watari; Akira Shiibashi; Akio Himizu; Takao Ikariya

doi:10.1021/ja1117254

Catalytic hydrogenation of carboxamides and esters by well-defined Cp*Ru complexes bearing a protic amine ligand

Masato Ito
, Takashi Ootsuka
, Ryo Watari
, Akira Shiibashi
, Akio Himizu
, Takao Ikariya

分子集積化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

195 被引用数 (Scopus)

抄録

A novel catalytic method for the straightforward hydrogenation of carboxamides and esters to primary alcohols has been developed. Chiral modification in the ligand sphere of the well-defined Cp*Ru catalyst molecule opens up a new possibility for the development of an enantioselective hydrogenation of racemic substrates via dynamic kinetic resolution.

本文言語	英語
ページ（範囲）	4240-4242
ページ数	3
ジャーナル	Journal of the American Chemical Society
巻	133
号	12
DOI	https://doi.org/10.1021/ja1117254
出版ステータス	出版済み - 3月 30 2011

!!!All Science Journal Classification (ASJC) codes

触媒
化学一般
生化学
コロイド化学および表面化学

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10.1021/ja1117254

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abstract = "A novel catalytic method for the straightforward hydrogenation of carboxamides and esters to primary alcohols has been developed. Chiral modification in the ligand sphere of the well-defined Cp*Ru catalyst molecule opens up a new possibility for the development of an enantioselective hydrogenation of racemic substrates via dynamic kinetic resolution.",

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AU - Ito, Masato

AU - Ootsuka, Takashi

AU - Watari, Ryo

AU - Shiibashi, Akira

AU - Himizu, Akio

AU - Ikariya, Takao

PY - 2011/3/30

Y1 - 2011/3/30

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AB - A novel catalytic method for the straightforward hydrogenation of carboxamides and esters to primary alcohols has been developed. Chiral modification in the ligand sphere of the well-defined Cp*Ru catalyst molecule opens up a new possibility for the development of an enantioselective hydrogenation of racemic substrates via dynamic kinetic resolution.

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Catalytic hydrogenation of carboxamides and esters by well-defined Cp*Ru complexes bearing a protic amine ligand

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!!!All Science Journal Classification (ASJC) codes

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