Bis(2,2′-bipyridine-κ 2N,N′)(1,10-phen-anthroline-κ 2N,N′)ruthenium(II) tetra-cyanoplatinate(II)

Ken Sakai; Yoshinobu Miyabe

doi:10.1107/S0108270103029500

Bis(2,2′-bipyridine-κ ²N,N′)(1,10-phen-anthroline-κ ²N,N′)ruthenium(II) tetra-cyanoplatinate(II)

Ken Sakai, Yoshinobu Miyabe

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

4 被引用数 (Scopus)

抄録

In the title compound, [Ru(C₁₀H₈N₂) ₂(C₁₂H₈N₂)][Pt(CN)₄], cations and anions alternate along the a axis to afford a one-dimensional network. The one-dimensional character arises from the π-π stacking as well as from the electrostatic interactions formed between the phen (1,10-phenanthroline) and [Pt(CN)₄]^2- units. Two adjacent one-dimensional chains form further stacks based on the π-π stacking interactions between the phen moieties, where the interplanar spacing is 3.50 (1) Å.

本文言語	英語
ページ（範囲）	m69-m72
ジャーナル	Acta Crystallographica Section C: Crystal Structure Communications
巻	60
号	2
DOI	https://doi.org/10.1107/S0108270103029500
出版ステータス	出版済み - 2月 1 2004
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

生化学、遺伝学、分子生物学（全般）

文献へのアクセス

10.1107/S0108270103029500

他のファイルとリンク

引用スタイル

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title = "Bis(2,2′-bipyridine-κ 2N,N′)(1,10-phen-anthroline-κ 2N,N′)ruthenium(II) tetra-cyanoplatinate(II)",

abstract = "In the title compound, [Ru(C10H8N2) 2(C12H8N2)][Pt(CN)4], cations and anions alternate along the a axis to afford a one-dimensional network. The one-dimensional character arises from the π-π stacking as well as from the electrostatic interactions formed between the phen (1,10-phenanthroline) and [Pt(CN)4]2- units. Two adjacent one-dimensional chains form further stacks based on the π-π stacking interactions between the phen moieties, where the interplanar spacing is 3.50 (1) {\AA}.",

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N2 - In the title compound, [Ru(C10H8N2) 2(C12H8N2)][Pt(CN)4], cations and anions alternate along the a axis to afford a one-dimensional network. The one-dimensional character arises from the π-π stacking as well as from the electrostatic interactions formed between the phen (1,10-phenanthroline) and [Pt(CN)4]2- units. Two adjacent one-dimensional chains form further stacks based on the π-π stacking interactions between the phen moieties, where the interplanar spacing is 3.50 (1) Å.

AB - In the title compound, [Ru(C10H8N2) 2(C12H8N2)][Pt(CN)4], cations and anions alternate along the a axis to afford a one-dimensional network. The one-dimensional character arises from the π-π stacking as well as from the electrostatic interactions formed between the phen (1,10-phenanthroline) and [Pt(CN)4]2- units. Two adjacent one-dimensional chains form further stacks based on the π-π stacking interactions between the phen moieties, where the interplanar spacing is 3.50 (1) Å.

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