Azaferrocene-Based PNP-Type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation

Shogo Kuriyama; Kazuya Arashiba; Kazunari Nakajima; Hiromasa Tanaka; Kazunari Yoshizawa; Yoshiaki Nishibayashi

doi:10.1002/ejic.201601051

Azaferrocene-Based PNP-Type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation

Shogo Kuriyama
, Kazuya Arashiba
, Kazunari Nakajima
, Hiromasa Tanaka
, Kazunari Yoshizawa
, Yoshiaki Nishibayashi

物質基盤化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

47 被引用数 (Scopus)

抄録

A series of azaferrocene-based PNP-type pincer ligands were designed and prepared as new PNP-type pincer ligands. Some transition-metal complexes, including molybdenum, chromium, and iron complexes, bearing these azaferrocene-based PNP-type pincer ligands were also prepared and characterized by X-ray analysis. The stoichiometric and catalytic reactivities of molybdenum–dinitrogen complexes toward nitrogen fixation were investigated in detail.

本文言語	英語
ページ（範囲）	4856-4861
ページ数	6
ジャーナル	European Journal of Inorganic Chemistry
巻	2016
号	30
DOI	https://doi.org/10.1002/ejic.201601051
出版ステータス	出版済み - 10月 2016

!!!All Science Journal Classification (ASJC) codes

無機化学

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10.1002/ejic.201601051

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引用スタイル

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abstract = "A series of azaferrocene-based PNP-type pincer ligands were designed and prepared as new PNP-type pincer ligands. Some transition-metal complexes, including molybdenum, chromium, and iron complexes, bearing these azaferrocene-based PNP-type pincer ligands were also prepared and characterized by X-ray analysis. The stoichiometric and catalytic reactivities of molybdenum–dinitrogen complexes toward nitrogen fixation were investigated in detail.",

author = "Shogo Kuriyama and Kazuya Arashiba and Kazunari Nakajima and Hiromasa Tanaka and Kazunari Yoshizawa and Yoshiaki Nishibayashi",

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AU - Nakajima, Kazunari

AU - Tanaka, Hiromasa

AU - Yoshizawa, Kazunari

AU - Nishibayashi, Yoshiaki

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JF - European Journal of Inorganic Chemistry

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