TY - JOUR
T1 - AuNU Dimers on ITO Substrate With the Highest Refractive Index Sensitivity as Chemical Sensor
AU - Chen, Bin
AU - Liu, Chuanjun
AU - Ge, Lingpu
AU - Shang, Liang
AU - Guo, Hao
AU - Hayashi, Kenshi
N1 - Publisher Copyright:
© 2001-2012 IEEE.
PY - 2022/4/15
Y1 - 2022/4/15
N2 - We synthesized gold (Au) nano-urchins (AuNUs) and deposited these AuNUs on indium tin oxide (ITO) glass. We compared the influence of the resistance of ITO glass and the deposition density of NUs on refractive index sensitivity (RIS) of these ITO substrates, and found that ITO glass with resistance of 8-12/sq and substrates with many AuNU dimers gave the highest RIS which was as high as 455 nm/RIU (refractive index unit), which is the highest on substrate as we known. Compared with AuNUs deposited on quartz glass, the extinction peak intensity and RIS were enhanced on ITO glass. The RIS enhancement is mainly attributed to the considerably enhanced electric field at the tips of AuNUs, electrical hot spots generated by AuNU aggregates (such as dimers), and the repulsive forces decrease in each AuNU by the ITO layer. It is thought that further shape, distribution, and size change of AuNUs and dimers on ITO glass will greatly affect the RIS and spectral characteristics. AuNU substrate is then proposed for heparin detection through Au etching. The results showed that heparin detection was realized in a linear range of 0.05 to 5μ g/mL with a detection limit of 8 ng/mL, which has potential to be applied in the practical environment.
AB - We synthesized gold (Au) nano-urchins (AuNUs) and deposited these AuNUs on indium tin oxide (ITO) glass. We compared the influence of the resistance of ITO glass and the deposition density of NUs on refractive index sensitivity (RIS) of these ITO substrates, and found that ITO glass with resistance of 8-12/sq and substrates with many AuNU dimers gave the highest RIS which was as high as 455 nm/RIU (refractive index unit), which is the highest on substrate as we known. Compared with AuNUs deposited on quartz glass, the extinction peak intensity and RIS were enhanced on ITO glass. The RIS enhancement is mainly attributed to the considerably enhanced electric field at the tips of AuNUs, electrical hot spots generated by AuNU aggregates (such as dimers), and the repulsive forces decrease in each AuNU by the ITO layer. It is thought that further shape, distribution, and size change of AuNUs and dimers on ITO glass will greatly affect the RIS and spectral characteristics. AuNU substrate is then proposed for heparin detection through Au etching. The results showed that heparin detection was realized in a linear range of 0.05 to 5μ g/mL with a detection limit of 8 ng/mL, which has potential to be applied in the practical environment.
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U2 - 10.1109/JSEN.2022.3155792
DO - 10.1109/JSEN.2022.3155792
M3 - Article
AN - SCOPUS:85125702353
SN - 1530-437X
VL - 22
SP - 7580
EP - 7589
JO - IEEE Sensors Journal
JF - IEEE Sensors Journal
IS - 8
ER -