Adsorption kinetics of silicic acid on akaganeite

Gaowa Naren, Hironori Ohashi, Yoshihiro Okaue, Takushi Yokoyama

研究成果: ジャーナルへの寄稿学術誌査読

10 被引用数 (Scopus)

抄録

As part of a series of studies on the interaction between ferric ions and silicic acid in the hydrosphere, the adsorption of silicic acid on akaganeite was investigated kinetically at various pH values. The adsorption of silicic acid increased with increasing pH over an initial pH range of 4-11.5. In the kinetic experiment, the Cl- was released from akaganeite much faster than silicic acid was adsorbed. From this result, we concluded that chloride ions bound on the surface of akaganeite are released and Fe-OH or Fe-O- sites are formed, which then acts as an adsorption site for silicic acid. The uptake mechanism of silicic acid by akaganeite is significantly different from that by schwertmannite, despite the presence of the same tunnel structure.

本文言語英語
ページ(範囲)87-91
ページ数5
ジャーナルJournal of Colloid And Interface Science
399
DOI
出版ステータス出版済み - 6月 1 2013

!!!All Science Journal Classification (ASJC) codes

  • 電子材料、光学材料、および磁性材料
  • 生体材料
  • 表面、皮膜および薄膜
  • コロイド化学および表面化学

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