A pH-stable ruthenium(II)-based sensing system for dissolved dinitrogen

Tetsuro Kizaki; Takeru Abe; Takahiro Matsumoto; Seiji Ogo

doi:10.1246/cl.2010.128

A pH-stable ruthenium(II)-based sensing system for dissolved dinitrogen

Tetsuro Kizaki
, Takeru Abe
, Takahiro Matsumoto
, Seiji Ogo

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

4 被引用数 (Scopus)

抄録

Building on a previous design for a Ru-based dissolved N ₂ sensor, we report an adaptation that allows for reversible data storage. The N ₂ complex can be "fixed" and made stable across a range of pHs by the substitution of OH ^- with F ^- to form [Ru ^II(F)(TMC)(N ₂)] ⁺ (1, TMC= l,4,8,11-tetramethyl-l,4,8,11tetraazacyclotetradecane). The addition of Ca2+ and irradiation with light at high pH removes the F ^-, thereby regenerating the sensor in its reversible configuration.

本文言語	英語
ページ（範囲）	128-129
ページ数	2
ジャーナル	Chemistry Letters
巻	39
号	2
DOI	https://doi.org/10.1246/cl.2010.128
出版ステータス	出版済み - 2010

!!!All Science Journal Classification (ASJC) codes

化学一般

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10.1246/cl.2010.128

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abstract = "Building on a previous design for a Ru-based dissolved N 2 sensor, we report an adaptation that allows for reversible data storage. The N 2 complex can be {"}fixed{"} and made stable across a range of pHs by the substitution of OH - with F - to form [Ru II(F)(TMC)(N 2)] + (1, TMC= l,4,8,11-tetramethyl-l,4,8,11tetraazacyclotetradecane). The addition of Ca2+ and irradiation with light at high pH removes the F -, thereby regenerating the sensor in its reversible configuration.",

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T1 - A pH-stable ruthenium(II)-based sensing system for dissolved dinitrogen

AU - Kizaki, Tetsuro

AU - Abe, Takeru

AU - Matsumoto, Takahiro

AU - Ogo, Seiji

PY - 2010

Y1 - 2010

N2 - Building on a previous design for a Ru-based dissolved N 2 sensor, we report an adaptation that allows for reversible data storage. The N 2 complex can be "fixed" and made stable across a range of pHs by the substitution of OH - with F - to form [Ru II(F)(TMC)(N 2)] + (1, TMC= l,4,8,11-tetramethyl-l,4,8,11tetraazacyclotetradecane). The addition of Ca2+ and irradiation with light at high pH removes the F -, thereby regenerating the sensor in its reversible configuration.

AB - Building on a previous design for a Ru-based dissolved N 2 sensor, we report an adaptation that allows for reversible data storage. The N 2 complex can be "fixed" and made stable across a range of pHs by the substitution of OH - with F - to form [Ru II(F)(TMC)(N 2)] + (1, TMC= l,4,8,11-tetramethyl-l,4,8,11tetraazacyclotetradecane). The addition of Ca2+ and irradiation with light at high pH removes the F -, thereby regenerating the sensor in its reversible configuration.

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UR - https://www.scopus.com/pages/publications/75749156604#tab=citedBy

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EP - 129

JO - Chemistry Letters

JF - Chemistry Letters

IS - 2

ER -

A pH-stable ruthenium(II)-based sensing system for dissolved dinitrogen

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!!!All Science Journal Classification (ASJC) codes

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