A Convenient Route to Ruthenium(IV)-Allyl Complexes (C5Me5)RuX2(η3-allyl) from [(C5Me5)RuCl2]n

Hideo Nagashima; Katsunori Mukai; Yusuke Shiota; Ken Ichi Ara; Kenji Itoh; Hiroharu Suzuki; Noriaki Oshima; Yoshihiko Moro-oka

doi:10.1021/om00126a036

A Convenient Route to Ruthenium(IV)-Allyl Complexes (C₅Me₅)RuX₂(η³-allyl) from [(C₅Me₅)RuCl₂]n

Hideo Nagashima
, Katsunori Mukai
, Yusuke Shiota
, Ken Ichi Ara
, Kenji Itoh
, Hiroharu Suzuki
, Noriaki Oshima
, Yoshihiko Moro-oka

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

39 被引用数 (Scopus)

抄録

Ruthenium(IV)-allyl complexes (C₅Me₅)-RuCl₂(η³-allyl) are easily prepared from a Ru(III) complex, [(C₅Me₅)RuCl₂]_n, by treatment with allylic halides, alcohol, ethers, acetate, or sulfides. Treatment of the resulting dichlororuthenium(IV) complex with aqueous HBr or HI solution resulted in smooth halogen-exchange reactions.

本文言語	英語
ページ（範囲）	1314-1315
ページ数	2
ジャーナル	Organometallics
巻	4
号	7
DOI	https://doi.org/10.1021/om00126a036
出版ステータス	出版済み - 7月 1985
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

物理化学および理論化学
有機化学
無機化学

文献へのアクセス

10.1021/om00126a036

他のファイルとリンク

引用スタイル

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title = "A Convenient Route to Ruthenium(IV)-Allyl Complexes (C5Me5)RuX2(η3-allyl) from [(C5Me5)RuCl2]n",

abstract = "Ruthenium(IV)-allyl complexes (C5Me5)-RuCl2(η3-allyl) are easily prepared from a Ru(III) complex, [(C5Me5)RuCl2]n, by treatment with allylic halides, alcohol, ethers, acetate, or sulfides. Treatment of the resulting dichlororuthenium(IV) complex with aqueous HBr or HI solution resulted in smooth halogen-exchange reactions.",

author = "Hideo Nagashima and Katsunori Mukai and Yusuke Shiota and Ara, \{Ken Ichi\} and Kenji Itoh and Hiroharu Suzuki and Noriaki Oshima and Yoshihiko Moro-oka",

year = "1985",

month = jul,

doi = "10.1021/om00126a036",

language = "English",

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pages = "1314--1315",

journal = "Organometallics",

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T1 - A Convenient Route to Ruthenium(IV)-Allyl Complexes (C5Me5)RuX2(η3-allyl) from [(C5Me5)RuCl2]n

AU - Nagashima, Hideo

AU - Mukai, Katsunori

AU - Shiota, Yusuke

AU - Ara, Ken Ichi

AU - Itoh, Kenji

AU - Suzuki, Hiroharu

AU - Oshima, Noriaki

AU - Moro-oka, Yoshihiko

PY - 1985/7

Y1 - 1985/7

N2 - Ruthenium(IV)-allyl complexes (C5Me5)-RuCl2(η3-allyl) are easily prepared from a Ru(III) complex, [(C5Me5)RuCl2]n, by treatment with allylic halides, alcohol, ethers, acetate, or sulfides. Treatment of the resulting dichlororuthenium(IV) complex with aqueous HBr or HI solution resulted in smooth halogen-exchange reactions.

AB - Ruthenium(IV)-allyl complexes (C5Me5)-RuCl2(η3-allyl) are easily prepared from a Ru(III) complex, [(C5Me5)RuCl2]n, by treatment with allylic halides, alcohol, ethers, acetate, or sulfides. Treatment of the resulting dichlororuthenium(IV) complex with aqueous HBr or HI solution resulted in smooth halogen-exchange reactions.

UR - https://www.scopus.com/pages/publications/0000161073

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U2 - 10.1021/om00126a036

DO - 10.1021/om00126a036

M3 - Article

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SN - 0276-7333

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JO - Organometallics

JF - Organometallics

IS - 7

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