@article{2838fee4e8d84ccdab1971ce9ee7fd96,
title = "5,15-Diheteroporphyrins synthesized from α,α'dihalodipyrrin as a key building block",
abstract = "A facile synthesis of meso-aryl-substituted α,α'-dihalodipyrrins and their use as starting materials in the porphyrin synthesis have enabled creation of various porphyrin analogues containing heteroatoms at two opposite meso-positions, namely 5,15-positions. Incorporation of lone pair electrons into the 18π-electron aromatic conjugated system of porphyrin allows the system to attain antiaromaticity with unique optical and electrochemical properties. This review summarizes the recent development in the chemistry of 5,15-diheteroporphyrins synthesized from meso-aryl-substituted α,α'-dihalodipyrrins.",
author = "Soji Shimizu",
note = "Funding Information: This work was supported by Grants-in-Aid for Scientific Research (B) (JSPS KAKENHI Grant no. JP19H02703), Challenging Exploratory Research (JSPS KAKENHI Grant no. JP18K19081) and Scientific Research on Innovative Area, {\textquoteleft}{\textquoteleft}π-System Figuration: Control of Electron and Structural Funding Information: This work was supported by Grants-in-Aid for Scientific Research (B) (JSPS KAKENHI Grant no. JP19H02703), Challenging Exploratory Research (JSPS KAKENHI Grant no. JP18K19081) and Scientific Research on Innovative Area, ''π-System Figuration: Control of Electron and Structural Dynamism for Innovative Functions (no. 2601)'' (JSPS KAKENHI Grant no. JP15H01001 and JP17H05160). Funding Information: Dynamism for Innovative Functions (no. 2601){\textquoteright}{\textquoteright} (JSPS KAKENHI Grant no. JP15H01001 and Publisher Copyright: {\textcopyright} 2020 The Japan Institute of Heterocyclic Chemistry",
year = "2020",
doi = "10.3987/REV-20-927",
language = "English",
volume = "100",
pages = "1123--1162",
journal = "Heterocycles",
issn = "0385-5414",
publisher = "Japan Institute of Heterocyclic Chemistry",
number = "8",
}