TY - JOUR
T1 - (4-Amino-2,2′-bipyridine)dichloroplatinum(II) dihydrate
AU - Sakai, Ken
AU - Yokoyama, Yoshimi
AU - Okamoto, Ken
AU - Takahashi, Satoru
PY - 2003/7/1
Y1 - 2003/7/1
N2 - In the crystal structure of the title compound, [PtCl2(C 10H9N3)]·2H2O, the square-planar platinum complexes form one-dimensional columns based on the π-π-stacking interactions between the 4-amino-2,2′-bipyridine ligands, where the plane-to-plane separations are 3.45 (1) and 3.47 (1) Å. The Pt⋯Pt distances in the column are 5.1214 (7) and 6.1648 (7) Å, suggesting no metal-metal interaction. Intermolecular hydrogen bonds are formed among the water molecules, the amino groups, and the coordinated Cl atoms.
AB - In the crystal structure of the title compound, [PtCl2(C 10H9N3)]·2H2O, the square-planar platinum complexes form one-dimensional columns based on the π-π-stacking interactions between the 4-amino-2,2′-bipyridine ligands, where the plane-to-plane separations are 3.45 (1) and 3.47 (1) Å. The Pt⋯Pt distances in the column are 5.1214 (7) and 6.1648 (7) Å, suggesting no metal-metal interaction. Intermolecular hydrogen bonds are formed among the water molecules, the amino groups, and the coordinated Cl atoms.
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U2 - 10.1107/S1600536803013552
DO - 10.1107/S1600536803013552
M3 - Article
AN - SCOPUS:18444416064
SN - 1600-5368
VL - 59
SP - m518-m520
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 7
ER -