3-Azidoarynes: Generation and Regioselective Reactions

Jumpei Taguchi; Kota Kimura; Kazunobu Igawa; Katsuhiko Tomooka; Takamitsu Hosoya

doi:10.1246/cl.210632

3-Azidoarynes: Generation and Regioselective Reactions

Jumpei Taguchi, Kota Kimura, Kazunobu Igawa, Katsuhiko Tomooka, Takamitsu Hosoya

分子集積化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

4 被引用数 (Scopus)

抄録

The generation of 3-azidoarynes from o-iodoaryl triflatetype precursors was achieved using a silylmethyl Grignard reagent as the activator. The azido group served to control the regioselectivity of the reaction of 3-azidoarynes with arynophiles. The remaining azido group in the adduct also served as a transformable functional group, enabling further derivatization to various nitrogen-containing compounds.

本文言語	英語
ページ（範囲）	94-98
ページ数	5
ジャーナル	Chemistry Letters
巻	51
号	2
DOI	https://doi.org/10.1246/cl.210632
出版ステータス	出版済み - 2月 2022

!!!All Science Journal Classification (ASJC) codes

化学一般

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10.1246/cl.210632

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abstract = "The generation of 3-azidoarynes from o-iodoaryl triflatetype precursors was achieved using a silylmethyl Grignard reagent as the activator. The azido group served to control the regioselectivity of the reaction of 3-azidoarynes with arynophiles. The remaining azido group in the adduct also served as a transformable functional group, enabling further derivatization to various nitrogen-containing compounds.",

author = "Jumpei Taguchi and Kota Kimura and Kazunobu Igawa and Katsuhiko Tomooka and Takamitsu Hosoya",

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doi = "10.1246/cl.210632",

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T2 - Generation and Regioselective Reactions

AU - Taguchi, Jumpei

AU - Kimura, Kota

AU - Igawa, Kazunobu

AU - Tomooka, Katsuhiko

AU - Hosoya, Takamitsu

PY - 2022/2

Y1 - 2022/2

N2 - The generation of 3-azidoarynes from o-iodoaryl triflatetype precursors was achieved using a silylmethyl Grignard reagent as the activator. The azido group served to control the regioselectivity of the reaction of 3-azidoarynes with arynophiles. The remaining azido group in the adduct also served as a transformable functional group, enabling further derivatization to various nitrogen-containing compounds.

AB - The generation of 3-azidoarynes from o-iodoaryl triflatetype precursors was achieved using a silylmethyl Grignard reagent as the activator. The azido group served to control the regioselectivity of the reaction of 3-azidoarynes with arynophiles. The remaining azido group in the adduct also served as a transformable functional group, enabling further derivatization to various nitrogen-containing compounds.

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JO - Chemistry Letters

JF - Chemistry Letters

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3-Azidoarynes: Generation and Regioselective Reactions

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!!!All Science Journal Classification (ASJC) codes

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