[2,3]Wittig rearrangement of enantiomerically-defined α-(allyloxy)stannanes: Solid evidence for inversion of configuration at the lithium- bearing migrating terminus

Katsuhiko Tomooka; Tatsuya Igarashi; Masashi Watanabe; Takeshi Nakai

doi:10.1016/0040-4039(92)89034-A

[2,3]Wittig rearrangement of enantiomerically-defined α-(allyloxy)stannanes: Solid evidence for inversion of configuration at the lithium- bearing migrating terminus

Katsuhiko Tomooka, Tatsuya Igarashi, Masashi Watanabe, Takeshi Nakai

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

68 被引用数 (Scopus)

抄録

The [2,3]Wittig rearrangement of enantiomerically-defined α-(allyloxy)stannanes, prepared from (S)-1-tributylstannyl-1-propanol, with butyllithium is shown to proceed with essentially complete inversion of configuration at the lithium-bearing migrating terminus. This inversion stereochemistry is further confirmed by the rearrangement of diastereomerically-defined α-(allyloxy)stannanes.

本文言語	英語
ページ（範囲）	5795-5798
ページ数	4
ジャーナル	Tetrahedron Letters
巻	33
号	39
DOI	https://doi.org/10.1016/0040-4039(92)89034-A
出版ステータス	出版済み - 9月 22 1992
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

生化学
創薬
有機化学

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10.1016/0040-4039(92)89034-A

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引用スタイル

[2,3]Wittig rearrangement of enantiomerically-defined α-(allyloxy)stannanes: Solid evidence for inversion of configuration at the lithium- bearing migrating terminus. / Tomooka, Katsuhiko; Igarashi, Tatsuya; Watanabe, Masashi その他.
In: Tetrahedron Letters, Vol. 33, No. 39, 22.09.1992, p. 5795-5798.

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

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