@article{bc201caa05154e4f97fab4be3f184c07,
title = "{\^I}-Glycosyl Trifluoroborates as Precursors for Direct {\^I}±-C-Glycosylation: Synthesis of 2-Deoxy-{\^I}±-C-glycosides",
abstract = "C-Glycosides are metabolically stable mimics of natural O-glycosides and are expected to be useful tools for investigation of the biological functions of glycans. Here, we describe the synthesis of a series of aryl and vinyl C-glycosides by stereoinvertive sp3-sp2 cross-coupling reactions of 2-deoxyglycosyl boronic acid derivatives with aryl or vinyl halide, mediated by a photoredox/nickel dual catalytic system. Hydrogenation of the vinyl C-glycosides afforded C-linked 2′-deoxydisaccharide analogues.",
author = "Daiki Takeda and Makoto Yoritate and Hiroki Yasutomi and Suzuka Chiba and Takahiro Moriyama and Atsushi Yokoo and Kazuteru Usui and Go Hirai",
note = "Funding Information: This study was partially supported by PRIME and the Platform Project for Supporting Drug Discovery and Life Science Research (BINDS) from the Japan Agency for Medical Research and Development, AMED, the JSPS KAKENHI (Grant Numbers 18H04417 for Middle Molecular Strategy, 18H02097, and 20K15957), the Naito Foundation, and the Sumitomo Foundation. Publisher Copyright: {\textcopyright} ",
year = "2021",
month = mar,
day = "5",
doi = "10.1021/acs.orglett.1c00402",
language = "English",
volume = "23",
pages = "1940--1944",
journal = "Organic letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "5",
}