TY - JOUR
T1 - X-ray absorption near-edge structure study on positive electrodes of degraded lithium-ion battery
AU - Shikano, Masahiro
AU - Kobayashi, Hironori
AU - Koike, Shinji
AU - Sakaebe, Hikari
AU - Saito, Yoshiyasu
AU - Hori, Hironobu
AU - Kageyama, Hiroyuki
AU - Tatsumi, Kuniaki
N1 - Funding Information:
Part of this work was carried out in the Li-EAD Project of the New Energy and Industrial Technology Development Organization (NEDO) in Japan. The authors are grateful to Dr. Shigemasa, Mr. Nakamura and Mr. Kondo of UVSOR and Dr. Tamenori of JASRI/SPring-8 for their support.
PY - 2011/8/15
Y1 - 2011/8/15
N2 - 18650-type cylindrical cells using LiNi1/3Mn 1/3Co1/3O2 (NMC) and hard carbon as positive and negative electrode material, respectively, were fabricated and degraded by cycle tests. The capacity of the cells remained more than 95% and 85% after cycle tests at 25 and 50 °C, respectively. After the cycle tests, Li-deficient cubic phase was observed on the surface of NMC. This phenomenon should be related to the degradation mechanism of this type of cell.
AB - 18650-type cylindrical cells using LiNi1/3Mn 1/3Co1/3O2 (NMC) and hard carbon as positive and negative electrode material, respectively, were fabricated and degraded by cycle tests. The capacity of the cells remained more than 95% and 85% after cycle tests at 25 and 50 °C, respectively. After the cycle tests, Li-deficient cubic phase was observed on the surface of NMC. This phenomenon should be related to the degradation mechanism of this type of cell.
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U2 - 10.1016/j.jpowsour.2011.01.042
DO - 10.1016/j.jpowsour.2011.01.042
M3 - Article
AN - SCOPUS:79958021800
SN - 0378-7753
VL - 196
SP - 6881
EP - 6883
JO - Journal of Power Sources
JF - Journal of Power Sources
IS - 16
ER -