TY - JOUR
T1 - Water-switching of spin transitions induced by metal-to-metal charge transfer in a microporous framework
AU - Liu, Tao
AU - Zhang, Yan Juan
AU - Kanegawa, Shinji
AU - Sato, Osamu
PY - 2010/11/8
Y1 - 2010/11/8
N2 - Water-switchable charge transfer: The microporous hydrated phase {[Fe(Tp)(CN)3]2Co(bpe)}5H2O shows spin transition induced by metal-to-metal charge transfer (MMCT), but no MMCT is observed in the corresponding dehydrated phase (see picture). Charge transfer can be reversibly switched through de- and rehydration. Tp=hydrotris(pyrazolyl) borate, bpe=1,2-bis(4-pyridyl)ethane. Fe green, Co orange, N blue, O red, C gray, B dark yellow.
AB - Water-switchable charge transfer: The microporous hydrated phase {[Fe(Tp)(CN)3]2Co(bpe)}5H2O shows spin transition induced by metal-to-metal charge transfer (MMCT), but no MMCT is observed in the corresponding dehydrated phase (see picture). Charge transfer can be reversibly switched through de- and rehydration. Tp=hydrotris(pyrazolyl) borate, bpe=1,2-bis(4-pyridyl)ethane. Fe green, Co orange, N blue, O red, C gray, B dark yellow.
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U2 - 10.1002/anie.201002881
DO - 10.1002/anie.201002881
M3 - Article
C2 - 20922730
AN - SCOPUS:78149425643
SN - 1433-7851
VL - 49
SP - 8645
EP - 8648
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 46
ER -