Viscoelastic properties of polystyrene–poly(vinyl methyl ether) blends in oscillatory and steady shear flows near the phase separation temperature

Yoshiaki Takahashi; Hirokazu Suzuki; Yoshiki Nakagawa; Ichiro Noda

doi:10.1002/pi.1994.210340313

Viscoelastic properties of polystyrene–poly(vinyl methyl ether) blends in oscillatory and steady shear flows near the phase separation temperature

Yoshiaki Takahashi, Hirokazu Suzuki, Yoshiki Nakagawa, Ichiro Noda

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Viscoelastic properties of a polystyrene‐poly(vinyl methyl ether) blend were measured in oscillatory and steady shear flows near the phase separation temperature. In the one‐phase region, the viscoelastic properties are independent of the type of flow and flow geometry, and their shear and frequency dependences are the same as those of homopolymers. When phase separation occurred, a change in viscoelastic properties was observed in all types of flow and flow geometries, and they are different in the different types of flow and/or different flow geometries in the two‐phase region. In the shear rate dependence of viscosity of the polymer blend in the two‐phase region at quiescence, a plateau region was observed, in which the shear viscosity can be regarded as the zero shear viscosity of the homogenized polymer blend at that temperature.

Original language	English
Pages (from-to)	327-331
Number of pages	5
Journal	Polymer International
Volume	34
Issue number	3
DOIs	https://doi.org/10.1002/pi.1994.210340313
Publication status	Published - Jul 1994
Externally published	Yes

All Science Journal Classification (ASJC) codes

Polymers and Plastics
Organic Chemistry
Materials Chemistry

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10.1002/pi.1994.210340313

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title = "Viscoelastic properties of polystyrene–poly(vinyl methyl ether) blends in oscillatory and steady shear flows near the phase separation temperature",

abstract = "Viscoelastic properties of a polystyrene‐poly(vinyl methyl ether) blend were measured in oscillatory and steady shear flows near the phase separation temperature. In the one‐phase region, the viscoelastic properties are independent of the type of flow and flow geometry, and their shear and frequency dependences are the same as those of homopolymers. When phase separation occurred, a change in viscoelastic properties was observed in all types of flow and flow geometries, and they are different in the different types of flow and/or different flow geometries in the two‐phase region. In the shear rate dependence of viscosity of the polymer blend in the two‐phase region at quiescence, a plateau region was observed, in which the shear viscosity can be regarded as the zero shear viscosity of the homogenized polymer blend at that temperature.",

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AU - Takahashi, Yoshiaki

AU - Suzuki, Hirokazu

AU - Nakagawa, Yoshiki

AU - Noda, Ichiro

PY - 1994/7

Y1 - 1994/7

N2 - Viscoelastic properties of a polystyrene‐poly(vinyl methyl ether) blend were measured in oscillatory and steady shear flows near the phase separation temperature. In the one‐phase region, the viscoelastic properties are independent of the type of flow and flow geometry, and their shear and frequency dependences are the same as those of homopolymers. When phase separation occurred, a change in viscoelastic properties was observed in all types of flow and flow geometries, and they are different in the different types of flow and/or different flow geometries in the two‐phase region. In the shear rate dependence of viscosity of the polymer blend in the two‐phase region at quiescence, a plateau region was observed, in which the shear viscosity can be regarded as the zero shear viscosity of the homogenized polymer blend at that temperature.

AB - Viscoelastic properties of a polystyrene‐poly(vinyl methyl ether) blend were measured in oscillatory and steady shear flows near the phase separation temperature. In the one‐phase region, the viscoelastic properties are independent of the type of flow and flow geometry, and their shear and frequency dependences are the same as those of homopolymers. When phase separation occurred, a change in viscoelastic properties was observed in all types of flow and flow geometries, and they are different in the different types of flow and/or different flow geometries in the two‐phase region. In the shear rate dependence of viscosity of the polymer blend in the two‐phase region at quiescence, a plateau region was observed, in which the shear viscosity can be regarded as the zero shear viscosity of the homogenized polymer blend at that temperature.

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Viscoelastic properties of polystyrene–poly(vinyl methyl ether) blends in oscillatory and steady shear flows near the phase separation temperature

Abstract

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