@article{2593c33c0ad6422bb0f2aa834d18ad5a,
title = "Vanadyl Species Catalyzed 1,2-Oxidative Trifluoromethylation of Unactivated Olefins",
abstract = "A catalytic protocol for {"}CF3{"}-radical type addition to terminal and β-substituted olefins with Togni's reagent to deliver various α-trifluoromethylated ketones of biomedicinal interests was examined by a series of oxovanadium species under oxygen atmosphere at ambient temperature. Among six different V(O)X2 bearing (bi)pyridine, imidazole, and (bis)oxazoline ligands and five different oxidovanadium complexes derived from N-salicylidene tert-leucinate, and salen ligands examined, the complexes with 3,5-dibromo substituents and VO(OTf)2 with bisoxazoline type ligands led to the best results.",
author = "Chen, {Chien Tien} and Chen, {Ya Pei} and Tsai, {Bang You} and Liao, {Yi Ya} and Su, {Yu Cheng} and Chen, {Tsung Cheng} and Lu, {Chia Hao} and Ryoma Fujii and Kyohei Kawashima and Seiji Mori",
note = "Funding Information: We thank the Ministry of Science and Technology of Taiwan (MOST) for financial support of this research. This work was partially supported by the “Frontier Research Center on Fundamental and Applied Sciences of Matters” from The Featured Areas Research Center Program within the framework of the Higher Education Sprout Project by the Ministry of Education (MOE) in Taiwan (109QR001I5 and NTHU 108QI009E1). This work was supported by a Grant-in-Aid for Scientific Research on Innovative Areas in “Precisely Designed Catalysts with Customized Scaffolding” (JSPS KAKENHI Grant Number JP18H04233 to S.M.) and by a Grant-in-Aid for Scientific Research (C) (JSPS KAKENHI Grant Number JP18K05072 to S.M.). The generous allotment of computation time from the Research Center for Computational Science, the National Institutes of Natural Sciences, Japan, is also gratefully acknowledged. Publisher Copyright: {\textcopyright} 2020 American Chemical Society.",
year = "2020",
month = mar,
day = "20",
doi = "10.1021/acscatal.0c00370",
language = "English",
volume = "10",
pages = "3676--3683",
journal = "ACS Catalysis",
issn = "2155-5435",
publisher = "American Chemical Society",
number = "6",
}