Utilization of industrially available 2,3-dichloro-1,3-butadiene for direct synthesis of 2,3-diaryl-1,3-butadienes

Takakazu Yamamoto; Takuma Yasuda; Kazuaki Kobayashi; Isao Yamaguchi; Take Aki Koizumi; Daisuke Ishii; Masaru Nakagawa; Yoshihiro Mashiko; Norihiro Shimizu

doi:10.1246/bcsj.79.498

Utilization of industrially available 2,3-dichloro-1,3-butadiene for direct synthesis of 2,3-diaryl-1,3-butadienes

Takakazu Yamamoto
, Takuma Yasuda
, Kazuaki Kobayashi
, Isao Yamaguchi
, Take Aki Koizumi
, Daisuke Ishii
, Masaru Nakagawa
, Yoshihiro Mashiko
, Norihiro Shimizu

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

It is shown that industrially available 2,3-dichloro-1,3-butadiene is a useful starting material for the synthesis of 2,3-diaryl-1,3-butadienes. Ni(II)-catalyzed cross-coupling reaction of 2,3-dichloro-1,3-butadiene with ArMgBr (Ar = 2-thienyl, phenyl, 4-dodecyloxyphenyl, and 4-fluorophenyl) gives the corresponding 2,3-diaryl-1,3-butadienes in good yields.

Original language	English
Pages (from-to)	498-500
Number of pages	3
Journal	Bulletin of the Chemical Society of Japan
Volume	79
Issue number	3
DOIs	https://doi.org/10.1246/bcsj.79.498
Publication status	Published - 2006
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry

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10.1246/bcsj.79.498

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title = "Utilization of industrially available 2,3-dichloro-1,3-butadiene for direct synthesis of 2,3-diaryl-1,3-butadienes",

abstract = "It is shown that industrially available 2,3-dichloro-1,3-butadiene is a useful starting material for the synthesis of 2,3-diaryl-1,3-butadienes. Ni(II)-catalyzed cross-coupling reaction of 2,3-dichloro-1,3-butadiene with ArMgBr (Ar = 2-thienyl, phenyl, 4-dodecyloxyphenyl, and 4-fluorophenyl) gives the corresponding 2,3-diaryl-1,3-butadienes in good yields.",

author = "Takakazu Yamamoto and Takuma Yasuda and Kazuaki Kobayashi and Isao Yamaguchi and Koizumi, \{Take Aki\} and Daisuke Ishii and Masaru Nakagawa and Yoshihiro Mashiko and Norihiro Shimizu",

year = "2006",

doi = "10.1246/bcsj.79.498",

language = "English",

volume = "79",

pages = "498--500",

journal = "Bulletin of the Chemical Society of Japan",

issn = "0009-2673",

publisher = "Oxford University Press",

number = "3",

}

TY - JOUR

T1 - Utilization of industrially available 2,3-dichloro-1,3-butadiene for direct synthesis of 2,3-diaryl-1,3-butadienes

AU - Yamamoto, Takakazu

AU - Yasuda, Takuma

AU - Kobayashi, Kazuaki

AU - Yamaguchi, Isao

AU - Koizumi, Take Aki

AU - Ishii, Daisuke

AU - Nakagawa, Masaru

AU - Mashiko, Yoshihiro

AU - Shimizu, Norihiro

PY - 2006

Y1 - 2006

N2 - It is shown that industrially available 2,3-dichloro-1,3-butadiene is a useful starting material for the synthesis of 2,3-diaryl-1,3-butadienes. Ni(II)-catalyzed cross-coupling reaction of 2,3-dichloro-1,3-butadiene with ArMgBr (Ar = 2-thienyl, phenyl, 4-dodecyloxyphenyl, and 4-fluorophenyl) gives the corresponding 2,3-diaryl-1,3-butadienes in good yields.

AB - It is shown that industrially available 2,3-dichloro-1,3-butadiene is a useful starting material for the synthesis of 2,3-diaryl-1,3-butadienes. Ni(II)-catalyzed cross-coupling reaction of 2,3-dichloro-1,3-butadiene with ArMgBr (Ar = 2-thienyl, phenyl, 4-dodecyloxyphenyl, and 4-fluorophenyl) gives the corresponding 2,3-diaryl-1,3-butadienes in good yields.

UR - https://www.scopus.com/pages/publications/33750510049

UR - https://www.scopus.com/pages/publications/33750510049#tab=citedBy

U2 - 10.1246/bcsj.79.498

DO - 10.1246/bcsj.79.498

M3 - Article

AN - SCOPUS:33750510049

SN - 0009-2673

VL - 79

SP - 498

EP - 500

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

IS - 3

ER -

Utilization of industrially available 2,3-dichloro-1,3-butadiene for direct synthesis of 2,3-diaryl-1,3-butadienes

Abstract

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