TY - JOUR
T1 - Unswollen layer of cross-linked polyisoprene at the solid interface
AU - Shimomura, Shinichiro
AU - Inutsuka, Manabu
AU - Yamada, Norifumi L.
AU - Tanaka, Keiji
N1 - Funding Information:
This work was partly supported by Grant-in-Aid for Young Scientists (B) (No. 15K17871 ) and Scientific Research (A) (no. 15H02183 ) from the Japan Society for the Promotion of Science (JSPS) . We are also grateful for support from the Japan Science and Technology Agency (JST) SENTANKEISOKU ( 13A0004 ) and Impulsing Paradigm Change through Disruptive Technologies Program (ImPACT). NR measurements were performed on BL-16 at the Materials and Life Science Facility, J-PARC, Japan , under Program No. 2009S08 , 2014S08 and 2016A0217 .
Funding Information:
This work was partly supported by Grant-in-Aid for Young Scientists (B) (No. 15K17871) and Scientific Research (A) (no. 15H02183) from the Japan Society for the Promotion of Science (JSPS). We are also grateful for support from the Japan Science and Technology Agency (JST) SENTANKEISOKU (13A0004) and Impulsing Paradigm Change through Disruptive Technologies Program (ImPACT). NR measurements were performed on BL-16 at the Materials and Life Science Facility, J-PARC, Japan, under Program No. 2009S08, 2014S08 and 2016A0217.
Publisher Copyright:
© 2016 Elsevier Ltd
PY - 2016/11/22
Y1 - 2016/11/22
N2 - The density profile in a thin cross-linked polyisoprene (PI) film spin-coated on a quartz substrate in n-hexane was examined by specular neutron reflectivity. We found two layers with different PI densities at the substrate interface. The characteristics of the layers are discussed in terms of bound rubber typically associated with the field of rubber materials and adsorbed layers typically associated with the field of glassy materials.
AB - The density profile in a thin cross-linked polyisoprene (PI) film spin-coated on a quartz substrate in n-hexane was examined by specular neutron reflectivity. We found two layers with different PI densities at the substrate interface. The characteristics of the layers are discussed in terms of bound rubber typically associated with the field of rubber materials and adsorbed layers typically associated with the field of glassy materials.
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U2 - 10.1016/j.polymer.2016.07.047
DO - 10.1016/j.polymer.2016.07.047
M3 - Article
AN - SCOPUS:84979695345
SN - 0032-3861
VL - 105
SP - 526
EP - 531
JO - polymer
JF - polymer
ER -