Unprecedented formation of a rhodium cluster triggered by rhodium-fastened N-confused gable porphyrin

Motoki Toganoh; Teppei Niino; Hiromitsu Maeda; Bruno Andrioletti; Hiroyuki Furuta

doi:10.1021/ic061741p

Unprecedented formation of a rhodium cluster triggered by rhodium-fastened N-confused gable porphyrin

Motoki Toganoh, Teppei Niino, Hiromitsu Maeda, Bruno Andrioletti, Hiroyuki Furuta

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Thermal reaction of N-confused porphyrin (NCP) with [RhCl(CO) ₂]₂ caused unprecedented formation of tetranuclear rhodium complex Rh₄(NCP)₂(CO)₄ having a gable-porphyrin-type structure, where two porphyrin π systems were electronically connected by the rhodium cluster.

Original language	English
Pages (from-to)	10428-10430
Number of pages	3
Journal	Inorganic chemistry
Volume	45
Issue number	26
DOIs	https://doi.org/10.1021/ic061741p
Publication status	Published - Dec 25 2006

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic061741p

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title = "Unprecedented formation of a rhodium cluster triggered by rhodium-fastened N-confused gable porphyrin",

abstract = "Thermal reaction of N-confused porphyrin (NCP) with [RhCl(CO) 2]2 caused unprecedented formation of tetranuclear rhodium complex Rh4(NCP)2(CO)4 having a gable-porphyrin-type structure, where two porphyrin π systems were electronically connected by the rhodium cluster.",

author = "Motoki Toganoh and Teppei Niino and Hiromitsu Maeda and Bruno Andrioletti and Hiroyuki Furuta",

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T1 - Unprecedented formation of a rhodium cluster triggered by rhodium-fastened N-confused gable porphyrin

AU - Toganoh, Motoki

AU - Niino, Teppei

AU - Maeda, Hiromitsu

AU - Andrioletti, Bruno

AU - Furuta, Hiroyuki

PY - 2006/12/25

Y1 - 2006/12/25

N2 - Thermal reaction of N-confused porphyrin (NCP) with [RhCl(CO) 2]2 caused unprecedented formation of tetranuclear rhodium complex Rh4(NCP)2(CO)4 having a gable-porphyrin-type structure, where two porphyrin π systems were electronically connected by the rhodium cluster.

AB - Thermal reaction of N-confused porphyrin (NCP) with [RhCl(CO) 2]2 caused unprecedented formation of tetranuclear rhodium complex Rh4(NCP)2(CO)4 having a gable-porphyrin-type structure, where two porphyrin π systems were electronically connected by the rhodium cluster.

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U2 - 10.1021/ic061741p

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M3 - Article

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JO - Inorganic chemistry

JF - Inorganic chemistry

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ER -

Unprecedented formation of a rhodium cluster triggered by rhodium-fastened N-confused gable porphyrin

Abstract

All Science Journal Classification (ASJC) codes

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