TY - JOUR
T1 - Unprecedented 1,4-methyl group migration in a rhodium-catalysed hydrosilylation of ketones by 1,2-bis(dimethylsilyl)benzene
AU - Nagashima, Hideo
AU - Tatebe, Kazuo
AU - Itoh, Kenji
PY - 1989
Y1 - 1989
N2 - A rhodium-catalyzed hydrosilylation of ketones afforded a mixture of alkoxysilanes, 1-(ROSiMe2)-2-(HMe2Si)C6H 4 and 1-(ROSiHMe)-2-(Me3Si)C6H4; the latter resulted by 1,4-methyl group migration during the hydrosilylation.
AB - A rhodium-catalyzed hydrosilylation of ketones afforded a mixture of alkoxysilanes, 1-(ROSiMe2)-2-(HMe2Si)C6H 4 and 1-(ROSiHMe)-2-(Me3Si)C6H4; the latter resulted by 1,4-methyl group migration during the hydrosilylation.
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U2 - 10.1039/p19890001707
DO - 10.1039/p19890001707
M3 - Article
AN - SCOPUS:37049084094
SN - 1472-7781
SP - 1707
EP - 1708
JO - Journal of the Chemical Society, Perkin Transactions 1
JF - Journal of the Chemical Society, Perkin Transactions 1
IS - 9
ER -