Unique spin transition and wide thermal hysteresis loop for a cobalt(ii) compound with long alkyl chain

Shinya Hayami; Kazuya Kato; Yasuka Komatsu; Akira Fuyuhiro; Masaaki Ohba

doi:10.1039/c0dt01052a

Unique spin transition and wide thermal hysteresis loop for a cobalt(ii) compound with long alkyl chain

Shinya Hayami
, Kazuya Kato
, Yasuka Komatsu
, Akira Fuyuhiro
, Masaaki Ohba

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

57 Citations (Scopus)

Abstract

The cobalt(ii) compounds with long alkyl chains, [Co(C12-terpy) ₂](BF₄)₂·EtOH·0.5H ₂O(1·EtOH·0.5H₂O) and [Co(C12-terpy) ₂](BF₄)₂ (1) was synthesized and characterized. The compound 1·EtOH·0.5H₂O exhibits a "re-entrant spin crossover". The compound 1 exhibits the reentrant spin crossover and multi phase transitions with a wide thermal hysteresis loop.

Original language	English
Pages (from-to)	2167-2169
Number of pages	3
Journal	Dalton Transactions
Volume	40
Issue number	10
DOIs	https://doi.org/10.1039/c0dt01052a
Publication status	Published - Mar 14 2011

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1039/c0dt01052a

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title = "Unique spin transition and wide thermal hysteresis loop for a cobalt(ii) compound with long alkyl chain",

abstract = "The cobalt(ii) compounds with long alkyl chains, [Co(C12-terpy) 2](BF4)2·EtOH·0.5H 2O(1·EtOH·0.5H2O) and [Co(C12-terpy) 2](BF4)2 (1) was synthesized and characterized. The compound 1·EtOH·0.5H2O exhibits a {"}re-entrant spin crossover{"}. The compound 1 exhibits the reentrant spin crossover and multi phase transitions with a wide thermal hysteresis loop.",

author = "Shinya Hayami and Kazuya Kato and Yasuka Komatsu and Akira Fuyuhiro and Masaaki Ohba",

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T1 - Unique spin transition and wide thermal hysteresis loop for a cobalt(ii) compound with long alkyl chain

AU - Hayami, Shinya

AU - Kato, Kazuya

AU - Komatsu, Yasuka

AU - Fuyuhiro, Akira

AU - Ohba, Masaaki

PY - 2011/3/14

Y1 - 2011/3/14

N2 - The cobalt(ii) compounds with long alkyl chains, [Co(C12-terpy) 2](BF4)2·EtOH·0.5H 2O(1·EtOH·0.5H2O) and [Co(C12-terpy) 2](BF4)2 (1) was synthesized and characterized. The compound 1·EtOH·0.5H2O exhibits a "re-entrant spin crossover". The compound 1 exhibits the reentrant spin crossover and multi phase transitions with a wide thermal hysteresis loop.

AB - The cobalt(ii) compounds with long alkyl chains, [Co(C12-terpy) 2](BF4)2·EtOH·0.5H 2O(1·EtOH·0.5H2O) and [Co(C12-terpy) 2](BF4)2 (1) was synthesized and characterized. The compound 1·EtOH·0.5H2O exhibits a "re-entrant spin crossover". The compound 1 exhibits the reentrant spin crossover and multi phase transitions with a wide thermal hysteresis loop.

UR - https://www.scopus.com/pages/publications/79951922248

UR - https://www.scopus.com/pages/publications/79951922248#tab=citedBy

U2 - 10.1039/c0dt01052a

DO - 10.1039/c0dt01052a

M3 - Article

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AN - SCOPUS:79951922248

SN - 1477-9226

VL - 40

SP - 2167

EP - 2169

JO - Dalton Transactions

JF - Dalton Transactions

IS - 10

ER -

Unique spin transition and wide thermal hysteresis loop for a cobalt(ii) compound with long alkyl chain

Abstract

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