Two step synthesis and characterization of thermally stable hexagonal zirconium phosphate

Wei Liu; Zhaoxia Song; Tasuku Ikegawa; Hiroyasu Nishiguchi; Tatsumi Ishihara; Yusaku Takita

doi:10.1016/j.matlet.2004.06.032

Two step synthesis and characterization of thermally stable hexagonal zirconium phosphate

Wei Liu, Zhaoxia Song, Tasuku Ikegawa, Hiroyasu Nishiguchi, Tatsumi Ishihara, Yusaku Takita

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Thermally stable hexagonal zirconium phosphate has been synthesized by a two-step method in which hexagonal zirconium sulfate surfactant composite is first produced by surfactant-assisted method and then subsequently treated in H₃PO₄ for long term. The ³¹P MAS NMR spectra show that the connectivity of phosphorus atoms increases from one ((Zr-O)PO ₃) or two ((Zr-O)₂PO₂) to three ((Zr-O) ₃PO) or four (P-O-P) upon calcination. There exists a significant number of surface Brönsted acid sites (Zr-O)₃POH on calcined sample. The high thermal stability of hexagonal zirconium phosphate is due to (Zr-O)₃PO and P-O-P connections, which build a network of zirconium phosphate.

Original language	English
Pages (from-to)	3328-3331
Number of pages	4
Journal	Materials Letters
Volume	58
Issue number	26
DOIs	https://doi.org/10.1016/j.matlet.2004.06.032
Publication status	Published - Oct 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Access to Document

10.1016/j.matlet.2004.06.032

Cite this

@article{729080ddeb4e45658f3ad53114913259,

title = "Two step synthesis and characterization of thermally stable hexagonal zirconium phosphate",

abstract = "Thermally stable hexagonal zirconium phosphate has been synthesized by a two-step method in which hexagonal zirconium sulfate surfactant composite is first produced by surfactant-assisted method and then subsequently treated in H3PO4 for long term. The 31P MAS NMR spectra show that the connectivity of phosphorus atoms increases from one ((Zr-O)PO 3) or two ((Zr-O)2PO2) to three ((Zr-O) 3PO) or four (P-O-P) upon calcination. There exists a significant number of surface Br{\"o}nsted acid sites (Zr-O)3POH on calcined sample. The high thermal stability of hexagonal zirconium phosphate is due to (Zr-O)3PO and P-O-P connections, which build a network of zirconium phosphate.",

author = "Wei Liu and Zhaoxia Song and Tasuku Ikegawa and Hiroyasu Nishiguchi and Tatsumi Ishihara and Yusaku Takita",

year = "2004",

month = oct,

doi = "10.1016/j.matlet.2004.06.032",

language = "English",

volume = "58",

pages = "3328--3331",

journal = "Materials Letters",

issn = "0167-577X",

publisher = "Elsevier",

number = "26",

}

TY - JOUR

T1 - Two step synthesis and characterization of thermally stable hexagonal zirconium phosphate

AU - Liu, Wei

AU - Song, Zhaoxia

AU - Ikegawa, Tasuku

AU - Nishiguchi, Hiroyasu

AU - Ishihara, Tatsumi

AU - Takita, Yusaku

PY - 2004/10

Y1 - 2004/10

N2 - Thermally stable hexagonal zirconium phosphate has been synthesized by a two-step method in which hexagonal zirconium sulfate surfactant composite is first produced by surfactant-assisted method and then subsequently treated in H3PO4 for long term. The 31P MAS NMR spectra show that the connectivity of phosphorus atoms increases from one ((Zr-O)PO 3) or two ((Zr-O)2PO2) to three ((Zr-O) 3PO) or four (P-O-P) upon calcination. There exists a significant number of surface Brönsted acid sites (Zr-O)3POH on calcined sample. The high thermal stability of hexagonal zirconium phosphate is due to (Zr-O)3PO and P-O-P connections, which build a network of zirconium phosphate.

AB - Thermally stable hexagonal zirconium phosphate has been synthesized by a two-step method in which hexagonal zirconium sulfate surfactant composite is first produced by surfactant-assisted method and then subsequently treated in H3PO4 for long term. The 31P MAS NMR spectra show that the connectivity of phosphorus atoms increases from one ((Zr-O)PO 3) or two ((Zr-O)2PO2) to three ((Zr-O) 3PO) or four (P-O-P) upon calcination. There exists a significant number of surface Brönsted acid sites (Zr-O)3POH on calcined sample. The high thermal stability of hexagonal zirconium phosphate is due to (Zr-O)3PO and P-O-P connections, which build a network of zirconium phosphate.

UR - http://www.scopus.com/inward/record.url?scp=4444356074&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=4444356074&partnerID=8YFLogxK

U2 - 10.1016/j.matlet.2004.06.032

DO - 10.1016/j.matlet.2004.06.032

M3 - Article

AN - SCOPUS:4444356074

SN - 0167-577X

VL - 58

SP - 3328

EP - 3331

JO - Materials Letters

JF - Materials Letters

IS - 26

ER -

Two step synthesis and characterization of thermally stable hexagonal zirconium phosphate

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this