Two new coordination polymers based on hexanuclear metal cluster cores

Jinxi Chen; Masaaki Ohba; Susumu Kitagawa

doi:10.1246/cl.2006.526

Two new coordination polymers based on hexanuclear metal cluster cores

Jinxi Chen, Masaaki Ohba, Susumu Kitagawa

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

Two new coordination polymers based on hexanuclear metal cluster cores, Zn₆(HCOO)₆(DBrTPA)₃(DMF)₆ (1) and Mn₆(HCOO)₆(BTC)₂(DMF)₆ (2) have been solvothermally synthesized. It is noteworthy that the formic ligands were in situ generated by the hydrolysis of DMF solvent under the solvothermal conditions and incorporated into these two compounds. The temperature-dependence of magnetic susceptibility for 2 shows antiferromagnetic interactions between metal centers.

Original language	English
Pages (from-to)	526-527
Number of pages	2
Journal	Chemistry Letters
Volume	35
Issue number	5
DOIs	https://doi.org/10.1246/cl.2006.526
Publication status	Published - May 5 2006
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

Access to Document

10.1246/cl.2006.526

Cite this

@article{c026b08e077c491e9187ec9687a7ff11,

title = "Two new coordination polymers based on hexanuclear metal cluster cores",

abstract = "Two new coordination polymers based on hexanuclear metal cluster cores, Zn6(HCOO)6(DBrTPA)3(DMF)6 (1) and Mn6(HCOO)6(BTC)2(DMF)6 (2) have been solvothermally synthesized. It is noteworthy that the formic ligands were in situ generated by the hydrolysis of DMF solvent under the solvothermal conditions and incorporated into these two compounds. The temperature-dependence of magnetic susceptibility for 2 shows antiferromagnetic interactions between metal centers.",

author = "Jinxi Chen and Masaaki Ohba and Susumu Kitagawa",

year = "2006",

month = may,

day = "5",

doi = "10.1246/cl.2006.526",

language = "English",

volume = "35",

pages = "526--527",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

number = "5",

}

TY - JOUR

T1 - Two new coordination polymers based on hexanuclear metal cluster cores

AU - Chen, Jinxi

AU - Ohba, Masaaki

AU - Kitagawa, Susumu

PY - 2006/5/5

Y1 - 2006/5/5

N2 - Two new coordination polymers based on hexanuclear metal cluster cores, Zn6(HCOO)6(DBrTPA)3(DMF)6 (1) and Mn6(HCOO)6(BTC)2(DMF)6 (2) have been solvothermally synthesized. It is noteworthy that the formic ligands were in situ generated by the hydrolysis of DMF solvent under the solvothermal conditions and incorporated into these two compounds. The temperature-dependence of magnetic susceptibility for 2 shows antiferromagnetic interactions between metal centers.

AB - Two new coordination polymers based on hexanuclear metal cluster cores, Zn6(HCOO)6(DBrTPA)3(DMF)6 (1) and Mn6(HCOO)6(BTC)2(DMF)6 (2) have been solvothermally synthesized. It is noteworthy that the formic ligands were in situ generated by the hydrolysis of DMF solvent under the solvothermal conditions and incorporated into these two compounds. The temperature-dependence of magnetic susceptibility for 2 shows antiferromagnetic interactions between metal centers.

UR - http://www.scopus.com/inward/record.url?scp=33746610188&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33746610188&partnerID=8YFLogxK

U2 - 10.1246/cl.2006.526

DO - 10.1246/cl.2006.526

M3 - Article

AN - SCOPUS:33746610188

SN - 0366-7022

VL - 35

SP - 526

EP - 527

JO - Chemistry Letters

JF - Chemistry Letters

IS - 5

ER -

Two new coordination polymers based on hexanuclear metal cluster cores

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this