TY - JOUR
T1 - Two coordination polymers of manganese(II) isophthalate and their preparation, structures, and magnetic properties
AU - Chen, Jinxi
AU - Wang, Jingjing
AU - Ohba, Masaaki
N1 - Funding Information:
The project was sponsored by the Natural Science Foundation of Jiangsu Province (No. BK2009262 ). MO thanks the Grant-In-Aid for Science Research in a Priority Area ‘Coordination Programming ( No. 22108512 )’ and the Grant-In-Aid for Scientific Research Program ( No. 23245014 ).
PY - 2012/1
Y1 - 2012/1
N2 - Two manganese coordination polymers, [Mn 2(ip) 2(dmf)]·dmf (1) and [Mn 4(ip) 4(dmf) 6]·2dmf (2) (ip=isophthalate; dmf=N,N-dimethylformamide), have been synthesized and characterized. X-ray crystal structural data reveal that compound 1 crystallizes in triclinic space group P-1, a=9.716(3) Å, b=12.193(3) Å, c=12.576(3) Å, α=62.19(2)°, β=66.423(17)°, γ=72.72(2)°, Z=2, while compound 2 crystallizes in monoclinic space group Cc, a=19.80(3) Å, b=20.20(2) Å, c=18.01(3) Å, β=108.40(4)°, Z=4. Variable-temperature magnetic susceptibilities of compounds 1 and 2 exhibit overall weak antiferromagnetic coupling between the adjacent Mn(II) ions.
AB - Two manganese coordination polymers, [Mn 2(ip) 2(dmf)]·dmf (1) and [Mn 4(ip) 4(dmf) 6]·2dmf (2) (ip=isophthalate; dmf=N,N-dimethylformamide), have been synthesized and characterized. X-ray crystal structural data reveal that compound 1 crystallizes in triclinic space group P-1, a=9.716(3) Å, b=12.193(3) Å, c=12.576(3) Å, α=62.19(2)°, β=66.423(17)°, γ=72.72(2)°, Z=2, while compound 2 crystallizes in monoclinic space group Cc, a=19.80(3) Å, b=20.20(2) Å, c=18.01(3) Å, β=108.40(4)°, Z=4. Variable-temperature magnetic susceptibilities of compounds 1 and 2 exhibit overall weak antiferromagnetic coupling between the adjacent Mn(II) ions.
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U2 - 10.1016/j.jssc.2011.10.051
DO - 10.1016/j.jssc.2011.10.051
M3 - Article
AN - SCOPUS:83855165671
SN - 0022-4596
VL - 185
SP - 37
EP - 41
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
ER -