TY - JOUR
T1 - Transition Metal-Catalyzed Synthesis of (E)-2-(Alkylthio)alka-1,3-dienes from Allenes and Dialkyl Disulfides with Concomitant Hydride Transfer
AU - Arisawa, Mieko
AU - Suwa, Atsushi
AU - Fujimoto, Kenji
AU - Yamaguchi, Masahiko
PY - 2003/5
Y1 - 2003/5
N2 - Reaction of dialkyl disulfides or diselenides with allenes is catalyzed by a rhodium-phosphine complex and trifluoromethanesulfonic acid giving (E)-2-alkylthio(seleno)-1,3-dienes and (E)-2-alkylthio(seleno)-2-alkenes. Unlike the reaction of alkynes, the reaction of allene is accompanied by hydride transfer.
AB - Reaction of dialkyl disulfides or diselenides with allenes is catalyzed by a rhodium-phosphine complex and trifluoromethanesulfonic acid giving (E)-2-alkylthio(seleno)-1,3-dienes and (E)-2-alkylthio(seleno)-2-alkenes. Unlike the reaction of alkynes, the reaction of allene is accompanied by hydride transfer.
UR - http://www.scopus.com/inward/record.url?scp=0038671661&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0038671661&partnerID=8YFLogxK
U2 - 10.1002/adsc.200303010
DO - 10.1002/adsc.200303010
M3 - Article
AN - SCOPUS:0038671661
SN - 1615-4150
VL - 345
SP - 560
EP - 563
JO - Advanced Synthesis and Catalysis
JF - Advanced Synthesis and Catalysis
IS - 5
ER -