Total synthesis of (+)-kuhistaferone

Mari Fujita; Mitsuru Shindo; Kozo Shishido

doi:10.1016/j.tetlet.2004.12.129

Total synthesis of (+)-kuhistaferone

Mari Fujita, Mitsuru Shindo, Kozo Shishido

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The first, enantiocontrolled total synthesis of (+)-kuhistaferone was achieved using an aluminum-based Lewis acid mediated rearrangement for the construction of a quaternary stereogenic center, an ene-reaction and an intramolecular Horner-Emmons reaction as the key steps.

Original language	English
Pages (from-to)	1269-1271
Number of pages	3
Journal	Tetrahedron Letters
Volume	46
Issue number	8
DOIs	https://doi.org/10.1016/j.tetlet.2004.12.129
Publication status	Published - Feb 21 2005
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2004.12.129

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abstract = "The first, enantiocontrolled total synthesis of (+)-kuhistaferone was achieved using an aluminum-based Lewis acid mediated rearrangement for the construction of a quaternary stereogenic center, an ene-reaction and an intramolecular Horner-Emmons reaction as the key steps.",

author = "Mari Fujita and Mitsuru Shindo and Kozo Shishido",

note = "Funding Information: We thank Professor Yoshihisa Takaishi and Dr. Kazuyoshi Kawazoe of our Department for providing us with the sample of natural kuhistaferone and its spectral data. This work was supported financially by a Grant-in-Aid for Scientific Research (A) (No. 16209001) from the Japan Society for the Promotion of Science.",

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AU - Fujita, Mari

AU - Shindo, Mitsuru

AU - Shishido, Kozo

N1 - Funding Information: We thank Professor Yoshihisa Takaishi and Dr. Kazuyoshi Kawazoe of our Department for providing us with the sample of natural kuhistaferone and its spectral data. This work was supported financially by a Grant-in-Aid for Scientific Research (A) (No. 16209001) from the Japan Society for the Promotion of Science.

PY - 2005/2/21

Y1 - 2005/2/21

N2 - The first, enantiocontrolled total synthesis of (+)-kuhistaferone was achieved using an aluminum-based Lewis acid mediated rearrangement for the construction of a quaternary stereogenic center, an ene-reaction and an intramolecular Horner-Emmons reaction as the key steps.

AB - The first, enantiocontrolled total synthesis of (+)-kuhistaferone was achieved using an aluminum-based Lewis acid mediated rearrangement for the construction of a quaternary stereogenic center, an ene-reaction and an intramolecular Horner-Emmons reaction as the key steps.

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DO - 10.1016/j.tetlet.2004.12.129

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 8

ER -

Total synthesis of (+)-kuhistaferone

Abstract

All Science Journal Classification (ASJC) codes

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