Time-resolved fluorescence analysis for dye-labeled polystyrene in thin films

Daisuke Kawaguchi, Yohei Tateishi, Keiji Tanaka

    Research output: Contribution to journalArticlepeer-review

    12 Citations (Scopus)

    Abstract

    Time-resolved fluorescence spectroscopy and anisotropy were applied to dye-labeled polystyrene in thin films. Both fluorescence lifetime and rotational relaxation time decreased with decreasing thickness once the film became thinner than approximately 100 nm. The results could be well reproduced by a tri-layer model composed of surface, interface and bulk regions. The model analysis clearly indicates that the chain dynamics in the surface and substrate interfacial regions is, respectively, faster and slower than that in the internal bulk phase.

    Original languageEnglish
    Pages (from-to)284-287
    Number of pages4
    JournalJournal of Non-Crystalline Solids
    Volume407
    DOIs
    Publication statusPublished - Jan 1 2015

    All Science Journal Classification (ASJC) codes

    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Condensed Matter Physics
    • Materials Chemistry

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