Three unprecedented open frameworks based on a pyridyl-carboxylate: Synthesis, structures and properties

Shengqun Su; Wan Chen; Xuezhi Song; Min Zhu; Chao Qin; Shuyan Song; Zhiyong Guo; Song Wang; Zhaoming Hao; Guanghua Li; Hongjie Zhang

doi:10.1039/c2ce05948g

Three unprecedented open frameworks based on a pyridyl-carboxylate: Synthesis, structures and properties

Shengqun Su, Wan Chen, Xuezhi Song, Min Zhu, Chao Qin, Shuyan Song, Zhiyong Guo, Song Wang, Zhaoming Hao, Guanghua Li, Hongjie Zhang

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Three open frameworks, [Ni(pnta) ₂]·1.3DMF (1), [Zn ₂(pnta) ₃(OH)]·2DMF (2), and [Cd(pnta) ₂]·3.8DMF (3), were obtained by solvothermal reactions between 6-(pyridin-4-yl)nicotinic acid (Hpnta) and nickel(II), zinc(II) and cadmium(II) nitrate, respectively. Compound 1 is a chiral framework with a fourfold interpenetrated diamondoid network structure and two types of chiral channels. Compound 2 also possesses the fourfold interpenetrated adamantanoid architecture with helical rhombic nanotube-like channels, each of which has two sides of double-layer walls and two other sides of single-layer walls. Compound 3 is a rarely reported double-walled framework with bcu topology. The luminescent properties of compounds 2 and 3 have been studied in the solid state at room temperature.

Original language	English
Pages (from-to)	1681-1686
Number of pages	6
Journal	CrystEngComm
Volume	14
Issue number	5
DOIs	https://doi.org/10.1039/c2ce05948g
Publication status	Published - Mar 7 2012
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Three unprecedented open frameworks based on a pyridyl-carboxylate: Synthesis, structures and properties",

abstract = "Three open frameworks, [Ni(pnta) 2]·1.3DMF (1), [Zn 2(pnta) 3(OH)]·2DMF (2), and [Cd(pnta) 2]·3.8DMF (3), were obtained by solvothermal reactions between 6-(pyridin-4-yl)nicotinic acid (Hpnta) and nickel(II), zinc(II) and cadmium(II) nitrate, respectively. Compound 1 is a chiral framework with a fourfold interpenetrated diamondoid network structure and two types of chiral channels. Compound 2 also possesses the fourfold interpenetrated adamantanoid architecture with helical rhombic nanotube-like channels, each of which has two sides of double-layer walls and two other sides of single-layer walls. Compound 3 is a rarely reported double-walled framework with bcu topology. The luminescent properties of compounds 2 and 3 have been studied in the solid state at room temperature.",

author = "Shengqun Su and Wan Chen and Xuezhi Song and Min Zhu and Chao Qin and Shuyan Song and Zhiyong Guo and Song Wang and Zhaoming Hao and Guanghua Li and Hongjie Zhang",

year = "2012",

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doi = "10.1039/c2ce05948g",

language = "English",

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T2 - Synthesis, structures and properties

AU - Su, Shengqun

AU - Chen, Wan

AU - Song, Xuezhi

AU - Zhu, Min

AU - Qin, Chao

AU - Song, Shuyan

AU - Guo, Zhiyong

AU - Wang, Song

AU - Hao, Zhaoming

AU - Li, Guanghua

AU - Zhang, Hongjie

PY - 2012/3/7

Y1 - 2012/3/7

N2 - Three open frameworks, [Ni(pnta) 2]·1.3DMF (1), [Zn 2(pnta) 3(OH)]·2DMF (2), and [Cd(pnta) 2]·3.8DMF (3), were obtained by solvothermal reactions between 6-(pyridin-4-yl)nicotinic acid (Hpnta) and nickel(II), zinc(II) and cadmium(II) nitrate, respectively. Compound 1 is a chiral framework with a fourfold interpenetrated diamondoid network structure and two types of chiral channels. Compound 2 also possesses the fourfold interpenetrated adamantanoid architecture with helical rhombic nanotube-like channels, each of which has two sides of double-layer walls and two other sides of single-layer walls. Compound 3 is a rarely reported double-walled framework with bcu topology. The luminescent properties of compounds 2 and 3 have been studied in the solid state at room temperature.

AB - Three open frameworks, [Ni(pnta) 2]·1.3DMF (1), [Zn 2(pnta) 3(OH)]·2DMF (2), and [Cd(pnta) 2]·3.8DMF (3), were obtained by solvothermal reactions between 6-(pyridin-4-yl)nicotinic acid (Hpnta) and nickel(II), zinc(II) and cadmium(II) nitrate, respectively. Compound 1 is a chiral framework with a fourfold interpenetrated diamondoid network structure and two types of chiral channels. Compound 2 also possesses the fourfold interpenetrated adamantanoid architecture with helical rhombic nanotube-like channels, each of which has two sides of double-layer walls and two other sides of single-layer walls. Compound 3 is a rarely reported double-walled framework with bcu topology. The luminescent properties of compounds 2 and 3 have been studied in the solid state at room temperature.

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Three unprecedented open frameworks based on a pyridyl-carboxylate: Synthesis, structures and properties

Abstract

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