Thiadiphosphetane disulfide as a metal extractant which shows high Ag+ selectivity

Masaaki Yoshifuji; Kozo Toyota; Kotaro Shirabe; Hideshi Iki; Takeshi Nagasaki; Seiji Shinkai

doi:10.1016/S0040-4039(00)73420-4

Thiadiphosphetane disulfide as a metal extractant which shows high Ag⁺ selectivity

Masaaki Yoshifuji, Kozo Toyota, Kotaro Shirabe, Hideshi Iki, Takeshi Nagasaki, Seiji Shinkai

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

It was shown that cis-2,4-bis(2,4,6-tri-tert-butylphenyl)-1,2,4-thiadiphosphetane 2,4-disulfide (1) acts as an excellent Ag⁺-selective extractant. Two-phase solvent-extraction and spectral examination with ¹H and ³¹P NMR established that 1 forms a 1:1 complex with Ag⁺ using the P(=S)-S-P(=S) linkage designed in the rigid four-membered ring.

Original language	English
Pages (from-to)	6313-6316
Number of pages	4
Journal	Tetrahedron Letters
Volume	35
Issue number	34
DOIs	https://doi.org/10.1016/S0040-4039(00)73420-4
Publication status	Published - Aug 22 1994
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)73420-4

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title = "Thiadiphosphetane disulfide as a metal extractant which shows high Ag+ selectivity",

abstract = "It was shown that cis-2,4-bis(2,4,6-tri-tert-butylphenyl)-1,2,4-thiadiphosphetane 2,4-disulfide (1) acts as an excellent Ag+-selective extractant. Two-phase solvent-extraction and spectral examination with 1H and 31P NMR established that 1 forms a 1:1 complex with Ag+ using the P(=S)-S-P(=S) linkage designed in the rigid four-membered ring.",

author = "Masaaki Yoshifuji and Kozo Toyota and Kotaro Shirabe and Hideshi Iki and Takeshi Nagasaki and Seiji Shinkai",

year = "1994",

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language = "English",

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journal = "Tetrahedron Letters",

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T1 - Thiadiphosphetane disulfide as a metal extractant which shows high Ag+ selectivity

AU - Yoshifuji, Masaaki

AU - Toyota, Kozo

AU - Shirabe, Kotaro

AU - Iki, Hideshi

AU - Nagasaki, Takeshi

AU - Shinkai, Seiji

PY - 1994/8/22

Y1 - 1994/8/22

N2 - It was shown that cis-2,4-bis(2,4,6-tri-tert-butylphenyl)-1,2,4-thiadiphosphetane 2,4-disulfide (1) acts as an excellent Ag+-selective extractant. Two-phase solvent-extraction and spectral examination with 1H and 31P NMR established that 1 forms a 1:1 complex with Ag+ using the P(=S)-S-P(=S) linkage designed in the rigid four-membered ring.

AB - It was shown that cis-2,4-bis(2,4,6-tri-tert-butylphenyl)-1,2,4-thiadiphosphetane 2,4-disulfide (1) acts as an excellent Ag+-selective extractant. Two-phase solvent-extraction and spectral examination with 1H and 31P NMR established that 1 forms a 1:1 complex with Ag+ using the P(=S)-S-P(=S) linkage designed in the rigid four-membered ring.

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U2 - 10.1016/S0040-4039(00)73420-4

DO - 10.1016/S0040-4039(00)73420-4

M3 - Article

AN - SCOPUS:0027933992

SN - 0040-4039

VL - 35

SP - 6313

EP - 6316

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 34

ER -

Thiadiphosphetane disulfide as a metal extractant which shows high Ag⁺ selectivity

Abstract

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