TY - JOUR
T1 - Thermal dissociation behavior of polymers with hemiacetal ester moieties in the side chain
T2 - The effect of structure on dissociation temperature
AU - Otsuka, Hideyuki
AU - Fujiwara, Hirotada
AU - Endo, Takeshi
PY - 1999/12/15
Y1 - 1999/12/15
N2 - The syntheses and thermal dissociation behaviors of polymers with hemiacetal ester structures in the side chain were examined by performing the radical polymerization of 1-alkoxypropyl and 1-alkoxyethyl methacrylates. The dissociation temperatures of the resulting polymers were influenced by their structures. The thermal dissociation behavior of the polymers was controllable by a simple molecular design of R1 and R2 units. The regeneration of carboxylic acids and vinyl ethers in the thermolysis of hemiacetal esters was detected by spectroscopic methods and supported by thermogravimetric measurements.
AB - The syntheses and thermal dissociation behaviors of polymers with hemiacetal ester structures in the side chain were examined by performing the radical polymerization of 1-alkoxypropyl and 1-alkoxyethyl methacrylates. The dissociation temperatures of the resulting polymers were influenced by their structures. The thermal dissociation behavior of the polymers was controllable by a simple molecular design of R1 and R2 units. The regeneration of carboxylic acids and vinyl ethers in the thermolysis of hemiacetal esters was detected by spectroscopic methods and supported by thermogravimetric measurements.
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U2 - 10.1002/(SICI)1099-0518(19991215)37:24<4478::AID-POLA2>3.0.CO;2-R
DO - 10.1002/(SICI)1099-0518(19991215)37:24<4478::AID-POLA2>3.0.CO;2-R
M3 - Article
AN - SCOPUS:0033279473
SN - 0887-624X
VL - 37
SP - 4478
EP - 4482
JO - Journal of Polymer Science, Part A: Polymer Chemistry
JF - Journal of Polymer Science, Part A: Polymer Chemistry
IS - 24
ER -