Thermal deposition method for p-n patterning of carbon nanotube sheets for planar-type thermoelectric generator

Ryohei Yamaguchi, Taiki Ishii, Masamichi Matsumoto, Angana Borah, Naoki Tanaka, Kaito Oda, Motohiro Tomita, Takanobu Watanabe, Tsuyohiko Fujigaya

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)


Thermoelectric generators (TEGs) using flexible single-walled carbon nanotube (SWCNT) sheets have a high Seebeck coefficient, remarkable electrical conductivity, and good flexibility, making them promising for the realization of wearable electronics. TEGs with a planar structure are preferable to those with π-shaped structures, as the planar surface enables the device to be attached flat to a surface such as skin. To realize a planar configuration, sequentially repeating p- and n-type areas must be fabricated with high precision. However, there is considerable molecular diffusion in the lateral directions when using solution doping methods, which decreases the patterning resolution. Therefore, in this study, a dry patterning process is developed based on thermal vapor deposition using patterned masks. For the patterning, p-type SWCNT sheets are doped using 2-(2-methoxyphenyl)-1,3-dimethyl-1H-benzoimidazol-3-ium iodide as the n-type dopant. The 50 μm-thick SWCNT sheets are doped from the top to the bottom of the sheet with a lateral diffusion of only ∼100 μm. Planar SWCNT-based TEGs with four p-n units exhibit an efficient power generation of 60 nW cm-2 (at ΔT = 25 °C), with scope for further optimization via simulation-based design.

Original languageEnglish
Pages (from-to)12188-12195
Number of pages8
JournalJournal of Materials Chemistry A
Issue number20
Publication statusPublished - May 28 2021

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • Renewable Energy, Sustainability and the Environment
  • General Materials Science


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