The synthesis of 2-halopentacenes and their charge transport properties

Ching Ting Chien; Motonori Watanabe; Tahsin J. Chow

doi:10.1016/j.tet.2015.01.056

The synthesis of 2-halopentacenes and their charge transport properties

Ching Ting Chien, Motonori Watanabe, Tahsin J. Chow

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Three 2-halo-subsituted pentacene derivatives were prepared from stable and soluble carbonyl adduct precursors of high purity in high yields. These precursors were synthesized from the corresponding anthraquinones in overall yields about 30%. The crystals of 2-substituted pentacenes were grown by using a method of physical vapor transport. Organic field effect transistors made with these crystals displayed p-type charge carrier characteristics with the highest hole mobility of 5.0 cm² V^-1 s^-1.

Original language	English
Pages (from-to)	1668-1673
Number of pages	6
Journal	Tetrahedron
Volume	71
Issue number	11
DOIs	https://doi.org/10.1016/j.tet.2015.01.056
Publication status	Published - Mar 18 2015

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tet.2015.01.056

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abstract = "Three 2-halo-subsituted pentacene derivatives were prepared from stable and soluble carbonyl adduct precursors of high purity in high yields. These precursors were synthesized from the corresponding anthraquinones in overall yields about 30%. The crystals of 2-substituted pentacenes were grown by using a method of physical vapor transport. Organic field effect transistors made with these crystals displayed p-type charge carrier characteristics with the highest hole mobility of 5.0 cm2 V-1 s-1.",

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note = "Funding Information: This work was supported by the National Science Council and Academia Sinica in Taiwan. The computations were carried out using the computer facilities at the Academia Sinica Computing Center. Publisher Copyright: {\textcopyright} 2015 Elsevier Ltd. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.",

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AU - Chow, Tahsin J.

N1 - Funding Information: This work was supported by the National Science Council and Academia Sinica in Taiwan. The computations were carried out using the computer facilities at the Academia Sinica Computing Center. Publisher Copyright: © 2015 Elsevier Ltd. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.

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N2 - Three 2-halo-subsituted pentacene derivatives were prepared from stable and soluble carbonyl adduct precursors of high purity in high yields. These precursors were synthesized from the corresponding anthraquinones in overall yields about 30%. The crystals of 2-substituted pentacenes were grown by using a method of physical vapor transport. Organic field effect transistors made with these crystals displayed p-type charge carrier characteristics with the highest hole mobility of 5.0 cm2 V-1 s-1.

AB - Three 2-halo-subsituted pentacene derivatives were prepared from stable and soluble carbonyl adduct precursors of high purity in high yields. These precursors were synthesized from the corresponding anthraquinones in overall yields about 30%. The crystals of 2-substituted pentacenes were grown by using a method of physical vapor transport. Organic field effect transistors made with these crystals displayed p-type charge carrier characteristics with the highest hole mobility of 5.0 cm2 V-1 s-1.

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The synthesis of 2-halopentacenes and their charge transport properties

Abstract

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