The synthesis, crystal structure and charge-transport properties of hexacene

Motonori Watanabe, Yuan Jay Chang, Shun Wei Liu, Ting Han Chao, Kenta Goto, Md Minarul Islam, Chih Hsien Yuan, Yu Tai Tao, Teruo Shinmyozu, Tahsin J. Chow

Research output: Contribution to journalArticlepeer-review

311 Citations (Scopus)


Acenes can be thought of as one-dimensional strips of graphene and they have the potential to be used in the next generation of electronic devices. However, because acenes larger than pentacene have been found to be unstable, it was generally accepted that they would not be particularly useful materials under normal conditions. Here, we show that, by using a physical vapour-transport method, platelet-shaped crystals of hexacene can be prepared from a monoketone precursor. These crystals are stable in the dark for a long period of time under ambient conditions. In the crystal, the molecules are arranged in herringbone arrays, quite similar to that observed for pentacene. A field-effect transistor made using a single crystal of hexacene displayed a hole mobility significantly higher than that of pentacene. This result suggests that it might be instructive to further explore the potential of other higher acenes.

Original languageEnglish
Pages (from-to)574-578
Number of pages5
JournalNature Chemistry
Issue number7
Publication statusPublished - Jul 2012

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • General Chemical Engineering


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