The first iron-catalysed aluminium-variant Negishi coupling: Critical effect of co-existing salts on the dynamic equilibrium of arylaluminium species and their reactivity

Shintaro Kawamura; Kentaro Ishizuka; Hikaru Takaya; Masaharu Nakamura

doi:10.1039/c0cc01216e

The first iron-catalysed aluminium-variant Negishi coupling: Critical effect of co-existing salts on the dynamic equilibrium of arylaluminium species and their reactivity

Shintaro Kawamura, Kentaro Ishizuka, Hikaru Takaya, Masaharu Nakamura

Research output: Contribution to journal › Article › peer-review

64 Citations (Scopus)

Abstract

The first example of an iron-catalysed Negishi coupling between arylaluminium reagents and alkyl halides illustrates that the co-existing salts highly influence the dynamic equilibrium of the organoaluminium species, and have a critical effect on the reactivity and selectivity of the coupling reaction.

Original language	English
Pages (from-to)	6054-6056
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	33
DOIs	https://doi.org/10.1039/c0cc01216e
Publication status	Published - Sept 7 2010
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c0cc01216e

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The first iron-catalysed aluminium-variant Negishi coupling: Critical effect of co-existing salts on the dynamic equilibrium of arylaluminium species and their reactivity. / Kawamura, Shintaro; Ishizuka, Kentaro; Takaya, Hikaru et al.
In: Chemical Communications, Vol. 46, No. 33, 07.09.2010, p. 6054-6056.

Research output: Contribution to journal › Article › peer-review

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The first iron-catalysed aluminium-variant Negishi coupling: Critical effect of co-existing salts on the dynamic equilibrium of arylaluminium species and their reactivity

Abstract

All Science Journal Classification (ASJC) codes

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