The first general method for Z-selective olefination of acylsilanes via ynolate anions providing multisubstituted alkenes

Mitsuru Shindo; Kenji Matsumoto; Seiji Mori; Kozo Shishido

doi:10.1021/ja026275r

The first general method for Z-selective olefination of acylsilanes via ynolate anions providing multisubstituted alkenes

Mitsuru Shindo, Kenji Matsumoto, Seiji Mori, Kozo Shishido

Research output: Contribution to journal › Article › peer-review

83 Citations (Scopus)

Abstract

We have developed the first general method for a stereoselective olefination of acylsilanes via ynolate anions to produce (Z)-ß-silyl-α,β-unsaturated ester, which leads to tri- and tetrasubstituted alkenes.

Original language	English
Pages (from-to)	6840-6841
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	124
Issue number	24
DOIs	https://doi.org/10.1021/ja026275r
Publication status	Published - Jun 19 2002
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja026275r

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abstract = "We have developed the first general method for a stereoselective olefination of acylsilanes via ynolate anions to produce (Z)-{\ss}-silyl-α,β-unsaturated ester, which leads to tri- and tetrasubstituted alkenes.",

author = "Mitsuru Shindo and Kenji Matsumoto and Seiji Mori and Kozo Shishido",

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AU - Shindo, Mitsuru

AU - Matsumoto, Kenji

AU - Mori, Seiji

AU - Shishido, Kozo

PY - 2002/6/19

Y1 - 2002/6/19

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AB - We have developed the first general method for a stereoselective olefination of acylsilanes via ynolate anions to produce (Z)-ß-silyl-α,β-unsaturated ester, which leads to tri- and tetrasubstituted alkenes.

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The first general method for Z-selective olefination of acylsilanes via ynolate anions providing multisubstituted alkenes

Abstract

All Science Journal Classification (ASJC) codes

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