The Effect of Additives in Room Temperature Molten Salt-based Lithium Battery Electrolytes

Minato Egashira; Toshiyasu Kiyabu; Izumi Watanabe; Shigeto Okada; Jun-ichi Yamaki

doi:10.5796/electrochemistry.71.1114

The Effect of Additives in Room Temperature Molten Salt-based Lithium Battery Electrolytes

Minato Egashira, Toshiyasu Kiyabu, Izumi Watanabe, Shigeto Okada, Jun-ichi Yamaki

Department of Advanced Device Materials

Research output: Contribution to journal › Article › peer-review

Abstract

Several organic solvent electrolytes used in lithium batteries were added to the electrolyte based on 1-ethyl-3-methyl imidazolium tetrafluoroborate (EMIBF4) in order to improve the deposition/dissolution behavior of lithium metal. The selected solvents for this purpose were ethylene carbonate (EC), dimethyl carbonate (DMC), and vinylene carbonate (VC). All of the selected electrolytes were effective in improving the reversible lithium deposition/dissolution on a steinless-steel electrode when added in 10 w/o. Among the selected solvents, VC provided the best behavior due to its good film-forming ability on the lithium surface in EMIBF4.

Original language	English
Pages (from-to)	1114-1116
Number of pages	3
Journal	Electrochemistry
Volume	71
Issue number	12
DOIs	https://doi.org/10.5796/electrochemistry.71.1114
Publication status	Published - Dec 5 2003

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title = "The Effect of Additives in Room Temperature Molten Salt-based Lithium Battery Electrolytes",

abstract = "Several organic solvent electrolytes used in lithium batteries were added to the electrolyte based on 1-ethyl-3-methyl imidazolium tetrafluoroborate (EMIBF4) in order to improve the deposition/dissolution behavior of lithium metal. The selected solvents for this purpose were ethylene carbonate (EC), dimethyl carbonate (DMC), and vinylene carbonate (VC). All of the selected electrolytes were effective in improving the reversible lithium deposition/dissolution on a steinless-steel electrode when added in 10 w/o. Among the selected solvents, VC provided the best behavior due to its good film-forming ability on the lithium surface in EMIBF4.",

author = "Minato Egashira and Toshiyasu Kiyabu and Izumi Watanabe and Shigeto Okada and Jun-ichi Yamaki",

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AU - Egashira, Minato

AU - Kiyabu, Toshiyasu

AU - Watanabe, Izumi

AU - Okada, Shigeto

AU - Yamaki, Jun-ichi

PY - 2003/12/5

Y1 - 2003/12/5

N2 - Several organic solvent electrolytes used in lithium batteries were added to the electrolyte based on 1-ethyl-3-methyl imidazolium tetrafluoroborate (EMIBF4) in order to improve the deposition/dissolution behavior of lithium metal. The selected solvents for this purpose were ethylene carbonate (EC), dimethyl carbonate (DMC), and vinylene carbonate (VC). All of the selected electrolytes were effective in improving the reversible lithium deposition/dissolution on a steinless-steel electrode when added in 10 w/o. Among the selected solvents, VC provided the best behavior due to its good film-forming ability on the lithium surface in EMIBF4.

AB - Several organic solvent electrolytes used in lithium batteries were added to the electrolyte based on 1-ethyl-3-methyl imidazolium tetrafluoroborate (EMIBF4) in order to improve the deposition/dissolution behavior of lithium metal. The selected solvents for this purpose were ethylene carbonate (EC), dimethyl carbonate (DMC), and vinylene carbonate (VC). All of the selected electrolytes were effective in improving the reversible lithium deposition/dissolution on a steinless-steel electrode when added in 10 w/o. Among the selected solvents, VC provided the best behavior due to its good film-forming ability on the lithium surface in EMIBF4.

U2 - 10.5796/electrochemistry.71.1114

DO - 10.5796/electrochemistry.71.1114

M3 - Article

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SP - 1114

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JO - Electrochemistry

JF - Electrochemistry

IS - 12

ER -

The Effect of Additives in Room Temperature Molten Salt-based Lithium Battery Electrolytes

Abstract

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