Tetrakis[pyridine-2(1H)-thione-κS]platinum(II) dichloride

Mina Mizota; Yoshimi Yokoyama; Ken Sakai

doi:10.1107/S1600536805020209

Tetrakis[pyridine-2(1H)-thione-κS]platinum(II) dichloride

Mina Mizota, Yoshimi Yokoyama, Ken Sakai

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

In the title compound, [Pt(C₅H₅NS) ₄]Cl₂, the Pt^II ion is located at a crystallographic inversion centre, with each S-donor ligand in its thione tautomeric form [Pt-S = 2.3439 (7) and 2.3444 (7) Å]. The Cl^- ion positioned at each axial site of the Pt^II ion [Pt⋯Cl = 3.5171 (8) Å] is hydrogen-bonded to the N-H units of the ligands [Cl⋯N = 3.103 (3) and 3.125 (3) Å].

Original language	English
Pages (from-to)	m1433-m1435
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	8
DOIs	https://doi.org/10.1107/S1600536805020209
Publication status	Published - Aug 1 2005

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Tetrakis[pyridine-2(1H)-thione-κS]platinum(II) dichloride",

abstract = "In the title compound, [Pt(C5H5NS) 4]Cl2, the PtII ion is located at a crystallographic inversion centre, with each S-donor ligand in its thione tautomeric form [Pt-S = 2.3439 (7) and 2.3444 (7) {\AA}]. The Cl- ion positioned at each axial site of the PtII ion [Pt⋯Cl = 3.5171 (8) {\AA}] is hydrogen-bonded to the N-H units of the ligands [Cl⋯N = 3.103 (3) and 3.125 (3) {\AA}].",

author = "Mina Mizota and Yoshimi Yokoyama and Ken Sakai",

year = "2005",

month = aug,

day = "1",

doi = "10.1107/S1600536805020209",

language = "English",

volume = "61",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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T1 - Tetrakis[pyridine-2(1H)-thione-κS]platinum(II) dichloride

AU - Mizota, Mina

AU - Yokoyama, Yoshimi

AU - Sakai, Ken

PY - 2005/8/1

Y1 - 2005/8/1

N2 - In the title compound, [Pt(C5H5NS) 4]Cl2, the PtII ion is located at a crystallographic inversion centre, with each S-donor ligand in its thione tautomeric form [Pt-S = 2.3439 (7) and 2.3444 (7) Å]. The Cl- ion positioned at each axial site of the PtII ion [Pt⋯Cl = 3.5171 (8) Å] is hydrogen-bonded to the N-H units of the ligands [Cl⋯N = 3.103 (3) and 3.125 (3) Å].

AB - In the title compound, [Pt(C5H5NS) 4]Cl2, the PtII ion is located at a crystallographic inversion centre, with each S-donor ligand in its thione tautomeric form [Pt-S = 2.3439 (7) and 2.3444 (7) Å]. The Cl- ion positioned at each axial site of the PtII ion [Pt⋯Cl = 3.5171 (8) Å] is hydrogen-bonded to the N-H units of the ligands [Cl⋯N = 3.103 (3) and 3.125 (3) Å].

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

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ER -

Tetrakis[pyridine-2(1H)-thione-κS]platinum(II) dichloride

Abstract

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