TY - JOUR
T1 - Synthesis, structures and magnetic properties of trinuclear M(II)A(II)M(II) complexes (M = Cu, Ni, Co; A = Pb, Ba) derived from 2,6-bis(acetoacetyl) pyridine
AU - Shiga, Takuya
AU - Nakanishi, Tatsuaki
AU - Ohba, Masaaki
AU - Okawa, Hisashi
N1 - Funding Information:
This work was supported by a Grant-in-Aid for Scientific Research Program (No. 13640561) from the Ministry of Education and Technology of Japan and Precursory Research for Embryonic Science and Technology (PRESTO), JST, Japan.
PY - 2005/11/17
Y1 - 2005/11/17
N2 - A series of trinuclear compounds [M2A(L)2(NO 3)2]·n(sol) (M = Cu(II), Ni(II), Co(II); A = Pb(II), Ba(II), H2L = 2,6-bis(acetoacetyl)pyridine, sol = H 2O or MeOH), has been systematically prepared by one-pot reaction of a M(II) nitrate salt, an A(II) nitrate salt and H2L in 2:1:2 ratio. They form a linear M(II)A(II)M(II) trinuclear core structure and show an antiferromagnetic interaction between the two terminal M(II) ions through the diamagnetic A(II) ion.
AB - A series of trinuclear compounds [M2A(L)2(NO 3)2]·n(sol) (M = Cu(II), Ni(II), Co(II); A = Pb(II), Ba(II), H2L = 2,6-bis(acetoacetyl)pyridine, sol = H 2O or MeOH), has been systematically prepared by one-pot reaction of a M(II) nitrate salt, an A(II) nitrate salt and H2L in 2:1:2 ratio. They form a linear M(II)A(II)M(II) trinuclear core structure and show an antiferromagnetic interaction between the two terminal M(II) ions through the diamagnetic A(II) ion.
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U2 - 10.1016/j.poly.2005.03.169
DO - 10.1016/j.poly.2005.03.169
M3 - Article
AN - SCOPUS:27644494187
SN - 0277-5387
VL - 24
SP - 2732
EP - 2736
JO - Polyhedron
JF - Polyhedron
IS - 16-17
ER -