TY - JOUR
T1 - Synthesis, structure and properties of novel homochiral metal-organic coordination polymers
AU - Chen, Wan
AU - Su, Sheng Qun
AU - Song, Shu Yan
AU - Song, Xue Zhi
AU - Zhang, Hong Jie
PY - 2012/2
Y1 - 2012/2
N2 - Two new homochiral metal-organic coordination polymers[M(D-cam)(H 2mbdpz)] n[M=Zn(complex 1), Co(complex 2); D-H 2cam=D-(+)-camphoric acid, H 2mbdpz=4, 4'-methylenebis(3, 5-dime-{thylpyrazole})] were prepared by mixing ligands with corresponding transition metal ions under hydrothermal conditions. The complexes were characterized by means of single-crystal X-ray diffraction, elemental analysis, thermograrimetri analysis(TGA), powder X-ray diffraction(XRD) and photoluminescent(PL) spectrometry. X-ray crystallography reveals that complexes 1 and 2 are isomorphous and homochiral, exhibiting the three-dimensional open structure with a ThSi 2 type of uninodal 3-connected networks.
AB - Two new homochiral metal-organic coordination polymers[M(D-cam)(H 2mbdpz)] n[M=Zn(complex 1), Co(complex 2); D-H 2cam=D-(+)-camphoric acid, H 2mbdpz=4, 4'-methylenebis(3, 5-dime-{thylpyrazole})] were prepared by mixing ligands with corresponding transition metal ions under hydrothermal conditions. The complexes were characterized by means of single-crystal X-ray diffraction, elemental analysis, thermograrimetri analysis(TGA), powder X-ray diffraction(XRD) and photoluminescent(PL) spectrometry. X-ray crystallography reveals that complexes 1 and 2 are isomorphous and homochiral, exhibiting the three-dimensional open structure with a ThSi 2 type of uninodal 3-connected networks.
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U2 - 10.3969/j.issn.0251-0790.2012.02.001
DO - 10.3969/j.issn.0251-0790.2012.02.001
M3 - Article
AN - SCOPUS:84863354303
SN - 0251-0790
VL - 33
SP - 215
EP - 218
JO - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
JF - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
IS - 2
ER -