Anionic polymerization of styrene derivatives para-substituted with adamantyl groups, 4-(1-adamantyl)styrene and 4-(1-adamantyl)-a-methylstyrene, proceeded quantitatively to afford well-defined polymers. We also attempted to introduce adamantyl group into the phenyl ring of polystyrenes by treatment with adamantyl triflate. The resulting polymers had significantly high Tg and thermal stability due to the introduced adamantyl moieties.
|Number of pages||1|
|Publication status||Published - 2006|
|Event||55th SPSJ Annual Meeting - Nagoya, Japan|
Duration: May 24 2006 → May 26 2006
|Other||55th SPSJ Annual Meeting|
|Period||5/24/06 → 5/26/06|
All Science Journal Classification (ASJC) codes