Synthesis of tetrasubstituted and functionalized enol ethers by E-selective olefination of esters with ynolates

Mitsuru Shindo; Taisuke Kita; Toshihiro Kumagai; Kenji Matsumoto; Kozo Shishido

doi:10.1021/ja0561082

Synthesis of tetrasubstituted and functionalized enol ethers by E-selective olefination of esters with ynolates

Mitsuru Shindo, Taisuke Kita, Toshihiro Kumagai, Kenji Matsumoto, Kozo Shishido

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

We have developed the E-selective olefination of ester carbonyls to afford tetrasubstituted, functionalized olefins and the C-S insertion of thiol esters to give β-keto thiol esters via ynolates.

Original language	English
Pages (from-to)	1062-1063
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	4
DOIs	https://doi.org/10.1021/ja0561082
Publication status	Published - Feb 1 2006

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja0561082

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title = "Synthesis of tetrasubstituted and functionalized enol ethers by E-selective olefination of esters with ynolates",

abstract = "We have developed the E-selective olefination of ester carbonyls to afford tetrasubstituted, functionalized olefins and the C-S insertion of thiol esters to give β-keto thiol esters via ynolates.",

author = "Mitsuru Shindo and Taisuke Kita and Toshihiro Kumagai and Kenji Matsumoto and Kozo Shishido",

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AU - Shindo, Mitsuru

AU - Kita, Taisuke

AU - Kumagai, Toshihiro

AU - Matsumoto, Kenji

AU - Shishido, Kozo

PY - 2006/2/1

Y1 - 2006/2/1

N2 - We have developed the E-selective olefination of ester carbonyls to afford tetrasubstituted, functionalized olefins and the C-S insertion of thiol esters to give β-keto thiol esters via ynolates.

AB - We have developed the E-selective olefination of ester carbonyls to afford tetrasubstituted, functionalized olefins and the C-S insertion of thiol esters to give β-keto thiol esters via ynolates.

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Synthesis of tetrasubstituted and functionalized enol ethers by E-selective olefination of esters with ynolates

Abstract

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