Synthesis of Redox-switchable 5,15-Dialkyl-10,20-diaryl-5,15-diazaporphyrins and Diversification of their N-Alkyl Groups

Mai Mutoh; Keisuke Sudoh; Ko Furukawa; Mao Minoura; Haruyuki Nakano; Yoshihiro Matano

doi:10.1002/ajoc.201900085

Synthesis of Redox-switchable 5,15-Dialkyl-10,20-diaryl-5,15-diazaporphyrins and Diversification of their N-Alkyl Groups

Mai Mutoh
, Keisuke Sudoh
, Ko Furukawa
, Mao Minoura
, Haruyuki Nakano
, Yoshihiro Matano

Multidisciplinary chemistry

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Nickel(II) and copper(II) complexes of redox-switchable 20π, 19π, and 18π 5,15-dialkyl-10,20-diaryl-5,15-diazaporphyrins were prepared through a metal-templated cyclization method. Furthermore, the terminal silyloxy groups in the peripheral N-alkyl chains were transformed into hydroxy groups by deprotection. It is worth noting that redox reactions between the 19π and 18π systems bearing hydroxy groups caused a change in the water solubility of the diazaporphyrin chromophore.

Original language	English
Pages (from-to)	352-355
Number of pages	4
Journal	Asian Journal of Organic Chemistry
Volume	8
Issue number	3
DOIs	https://doi.org/10.1002/ajoc.201900085
Publication status	Published - Mar 2019

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1002/ajoc.201900085

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abstract = "Nickel(II) and copper(II) complexes of redox-switchable 20π, 19π, and 18π 5,15-dialkyl-10,20-diaryl-5,15-diazaporphyrins were prepared through a metal-templated cyclization method. Furthermore, the terminal silyloxy groups in the peripheral N-alkyl chains were transformed into hydroxy groups by deprotection. It is worth noting that redox reactions between the 19π and 18π systems bearing hydroxy groups caused a change in the water solubility of the diazaporphyrin chromophore.",

author = "Mai Mutoh and Keisuke Sudoh and Ko Furukawa and Mao Minoura and Haruyuki Nakano and Yoshihiro Matano",

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T1 - Synthesis of Redox-switchable 5,15-Dialkyl-10,20-diaryl-5,15-diazaporphyrins and Diversification of their N-Alkyl Groups

AU - Mutoh, Mai

AU - Sudoh, Keisuke

AU - Furukawa, Ko

AU - Minoura, Mao

AU - Nakano, Haruyuki

AU - Matano, Yoshihiro

PY - 2019/3

Y1 - 2019/3

N2 - Nickel(II) and copper(II) complexes of redox-switchable 20π, 19π, and 18π 5,15-dialkyl-10,20-diaryl-5,15-diazaporphyrins were prepared through a metal-templated cyclization method. Furthermore, the terminal silyloxy groups in the peripheral N-alkyl chains were transformed into hydroxy groups by deprotection. It is worth noting that redox reactions between the 19π and 18π systems bearing hydroxy groups caused a change in the water solubility of the diazaporphyrin chromophore.

AB - Nickel(II) and copper(II) complexes of redox-switchable 20π, 19π, and 18π 5,15-dialkyl-10,20-diaryl-5,15-diazaporphyrins were prepared through a metal-templated cyclization method. Furthermore, the terminal silyloxy groups in the peripheral N-alkyl chains were transformed into hydroxy groups by deprotection. It is worth noting that redox reactions between the 19π and 18π systems bearing hydroxy groups caused a change in the water solubility of the diazaporphyrin chromophore.

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JO - Asian Journal of Organic Chemistry

JF - Asian Journal of Organic Chemistry

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ER -

Synthesis of Redox-switchable 5,15-Dialkyl-10,20-diaryl-5,15-diazaporphyrins and Diversification of their N-Alkyl Groups

Abstract

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