Synthesis of aqueous-stable and water-soluble mononuclear nonheme MnV-Oxo complexes using H2O2as an oxidant

Takeshi Yatabe, Takahiro Kikunaga, Takahiro Matsumoto, Hidetaka Nakai, Ki Seok Yoon, Seiji Ogo

    Research output: Contribution to journalArticlepeer-review

    2 Citations (Scopus)

    Abstract

    We report the synthesis of mononuclear nonheme manganese(V)oxo complexes in aqueous acetonitrile solution from the reaction of manganese(III) complexes using hydrogen peroxide as an oxidant for the first time. A crystal structure of chloro derivative of manganese(V)oxo complex and its reactivity toward 3,5-di-tert-butyl-catechol are also reported.

    Original languageEnglish
    Pages (from-to)1380-1382
    Number of pages3
    JournalChemistry Letters
    Volume43
    Issue number8
    DOIs
    Publication statusPublished - 2014

    All Science Journal Classification (ASJC) codes

    • General Chemistry

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