Synthesis, characterization, and activation of thermally stable μ-1,2-peroxodiiron(III) complex

M. Kodera; Y. Taniike; M. Itoh; Y. Tanahashi; H. Shimakoshi; K. Kano; S. Hirota; S. Iijima; M. Ohba; H. Okawa

doi:10.1021/ic0155434

Synthesis, characterization, and activation of thermally stable μ-1,2-peroxodiiron(III) complex

M. Kodera
, Y. Taniike
, M. Itoh
, Y. Tanahashi
, H. Shimakoshi
, K. Kano
, S. Hirota
, S. Iijima
, M. Ohba
, H. Okawa

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

A thermally stable (μ-acetato)μ-oxo)μ-1,2-peroxo)-diiron(III) complex [Fe₂(O₂)(O)(OAc)(L) ](CF₃SO₃) {L: 1,2-bis[2-(bis(2-pyridyl)methyl)-6-pyridyl]ethane} has been isolated, characterized, and activated. [Fe₂-(O₂)(O)(OAc)(L)](CF₃SO₃) in MeCN is thermally stable; the half-life time τ_1/2 = 7.7 h at 300 K. [Fe₂-(O₂)(O)(OAc)(L)](CF₃SO₃) is activated upon addition of RCOCl (R = m-ClC₆H₄, CH₃, and CCl₃) in the presence of DMF to oxygenate cyclohexane and cyclohexene to the corresponding alcohols and ketones.

Original language	English
Pages (from-to)	4821-4822
Number of pages	2
Journal	Inorganic chemistry
Volume	40
Issue number	19
DOIs	https://doi.org/10.1021/ic0155434
Publication status	Published - Sept 10 2001

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic0155434

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@article{0c5d11ec218f482ea4b909f97d205550,

title = "Synthesis, characterization, and activation of thermally stable μ-1,2-peroxodiiron(III) complex",

abstract = "A thermally stable (μ-acetato)μ-oxo)μ-1,2-peroxo)-diiron(III) complex [Fe2(O2)(O)(OAc)(L) ](CF3SO3) \{L: 1,2-bis[2-(bis(2-pyridyl)methyl)-6-pyridyl]ethane\} has been isolated, characterized, and activated. [Fe2-(O2)(O)(OAc)(L)](CF3SO3) in MeCN is thermally stable; the half-life time τ1/2 = 7.7 h at 300 K. [Fe2-(O2)(O)(OAc)(L)](CF3SO3) is activated upon addition of RCOCl (R = m-ClC6H4, CH3, and CCl3) in the presence of DMF to oxygenate cyclohexane and cyclohexene to the corresponding alcohols and ketones.",

author = "M. Kodera and Y. Taniike and M. Itoh and Y. Tanahashi and H. Shimakoshi and K. Kano and S. Hirota and S. Iijima and M. Ohba and H. Okawa",

year = "2001",

month = sep,

day = "10",

doi = "10.1021/ic0155434",

language = "English",

volume = "40",

pages = "4821--4822",

journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "19",

}

TY - JOUR

T1 - Synthesis, characterization, and activation of thermally stable μ-1,2-peroxodiiron(III) complex

AU - Kodera, M.

AU - Taniike, Y.

AU - Itoh, M.

AU - Tanahashi, Y.

AU - Shimakoshi, H.

AU - Kano, K.

AU - Hirota, S.

AU - Iijima, S.

AU - Ohba, M.

AU - Okawa, H.

PY - 2001/9/10

Y1 - 2001/9/10

N2 - A thermally stable (μ-acetato)μ-oxo)μ-1,2-peroxo)-diiron(III) complex [Fe2(O2)(O)(OAc)(L) ](CF3SO3) {L: 1,2-bis[2-(bis(2-pyridyl)methyl)-6-pyridyl]ethane} has been isolated, characterized, and activated. [Fe2-(O2)(O)(OAc)(L)](CF3SO3) in MeCN is thermally stable; the half-life time τ1/2 = 7.7 h at 300 K. [Fe2-(O2)(O)(OAc)(L)](CF3SO3) is activated upon addition of RCOCl (R = m-ClC6H4, CH3, and CCl3) in the presence of DMF to oxygenate cyclohexane and cyclohexene to the corresponding alcohols and ketones.

AB - A thermally stable (μ-acetato)μ-oxo)μ-1,2-peroxo)-diiron(III) complex [Fe2(O2)(O)(OAc)(L) ](CF3SO3) {L: 1,2-bis[2-(bis(2-pyridyl)methyl)-6-pyridyl]ethane} has been isolated, characterized, and activated. [Fe2-(O2)(O)(OAc)(L)](CF3SO3) in MeCN is thermally stable; the half-life time τ1/2 = 7.7 h at 300 K. [Fe2-(O2)(O)(OAc)(L)](CF3SO3) is activated upon addition of RCOCl (R = m-ClC6H4, CH3, and CCl3) in the presence of DMF to oxygenate cyclohexane and cyclohexene to the corresponding alcohols and ketones.

UR - https://www.scopus.com/pages/publications/0035840203

UR - https://www.scopus.com/pages/publications/0035840203#tab=citedBy

U2 - 10.1021/ic0155434

DO - 10.1021/ic0155434

M3 - Article

C2 - 11531426

AN - SCOPUS:0035840203

SN - 0020-1669

VL - 40

SP - 4821

EP - 4822

JO - Inorganic chemistry

JF - Inorganic chemistry

IS - 19

ER -

Synthesis, characterization, and activation of thermally stable μ-1,2-peroxodiiron(III) complex

Abstract

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