Synthesis and structure of a water-soluble μ-η1:η1-N2 dinuclear RuII complex with a polyamine ligand

Koji Yoshimoto; Takeshi Yatabe; Takahiro Matsumoto; Andrew Robertson; Hidetaka Nakai; Hiromasa Tanaka; Takashi Kamachi; Yoshihito Shiota; Kazunari Yoshizawa; Koichiro Asazawa; Hirohisa Tanaka; Seiji Ogo

doi:10.1246/cl.151004

Synthesis and structure of a water-soluble μ-η¹:η¹-N₂ dinuclear Ru^II complex with a polyamine ligand

Koji Yoshimoto, Takeshi Yatabe, Takahiro Matsumoto, Andrew Robertson, Hidetaka Nakai, Hiromasa Tanaka, Takashi Kamachi, Yoshihito Shiota, Kazunari Yoshizawa, Koichiro Asazawa, Hirohisa Tanaka, Seiji Ogo

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3 Citations (Scopus)

Abstract

We report the first example of a μ-η¹:η¹-N₂ dinuclear Ru^II complex with a polyamine ligand and elucidate the structure by means of X-ray analysis. The N=N stretching vibration has been observed at 1994 cm^-1 by Raman spectroscopy, which is the lowest value of all the known N₂-coordinated RuII complexes. This low value strongly suggests the N=N bond is primed for activation.

Original language	English
Pages (from-to)	149-151
Number of pages	3
Journal	Chemistry Letters
Volume	45
Issue number	2
DOIs	https://doi.org/10.1246/cl.151004
Publication status	Published - 2016

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.151004

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title = "Synthesis and structure of a water-soluble μ-η1:η1-N2 dinuclear RuII complex with a polyamine ligand",

abstract = "We report the first example of a μ-η1:η1-N2 dinuclear RuII complex with a polyamine ligand and elucidate the structure by means of X-ray analysis. The N=N stretching vibration has been observed at 1994 cm-1 by Raman spectroscopy, which is the lowest value of all the known N2-coordinated RuII complexes. This low value strongly suggests the N=N bond is primed for activation.",

author = "Koji Yoshimoto and Takeshi Yatabe and Takahiro Matsumoto and Andrew Robertson and Hidetaka Nakai and Hiromasa Tanaka and Takashi Kamachi and Yoshihito Shiota and Kazunari Yoshizawa and Koichiro Asazawa and Hirohisa Tanaka and Seiji Ogo",

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T1 - Synthesis and structure of a water-soluble μ-η1:η1-N2 dinuclear RuII complex with a polyamine ligand

AU - Yoshimoto, Koji

AU - Yatabe, Takeshi

AU - Matsumoto, Takahiro

AU - Robertson, Andrew

AU - Nakai, Hidetaka

AU - Tanaka, Hiromasa

AU - Kamachi, Takashi

AU - Shiota, Yoshihito

AU - Yoshizawa, Kazunari

AU - Asazawa, Koichiro

AU - Tanaka, Hirohisa

AU - Ogo, Seiji

PY - 2016

Y1 - 2016

N2 - We report the first example of a μ-η1:η1-N2 dinuclear RuII complex with a polyamine ligand and elucidate the structure by means of X-ray analysis. The N=N stretching vibration has been observed at 1994 cm-1 by Raman spectroscopy, which is the lowest value of all the known N2-coordinated RuII complexes. This low value strongly suggests the N=N bond is primed for activation.

AB - We report the first example of a μ-η1:η1-N2 dinuclear RuII complex with a polyamine ligand and elucidate the structure by means of X-ray analysis. The N=N stretching vibration has been observed at 1994 cm-1 by Raman spectroscopy, which is the lowest value of all the known N2-coordinated RuII complexes. This low value strongly suggests the N=N bond is primed for activation.

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JF - Chemistry Letters

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ER -

Synthesis and structure of a water-soluble μ-η¹:η¹-N₂ dinuclear Ru^II complex with a polyamine ligand

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