Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene

Mitsuo Ishikawa; Junnai Ikadai; Akinobu Naka; Joji Ohshita; Atsutaka Kunai; Kazunari Yoshizawa; Song Yun Kang; Tokio Yamabe

doi:10.1021/om000909q

Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene

Mitsuo Ishikawa
, Junnai Ikadai
, Akinobu Naka
, Joji Ohshita
, Atsutaka Kunai
, Kazunari Yoshizawa
, Song Yun Kang
, Tokio Yamabe

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The reactions of pure cis- and trans-3,4-benzo-1,2-di(tert-butyl)-1, 2-dimethyl-1,2-disilacyclobut-3-ene (1a and 1b) with oxygen in the presence of AIBN proceeded stereospecifically to give the respective siloxanes. The palladium-catalyzed reactions of 1a and 1b with phenylacetylene and 1-hexyne produced stereospecifically cis- and trans-5,6-benzo-1,4-disilacyclohexa-2,5-dienes.

Original language	English
Pages (from-to)	1059-1061
Number of pages	3
Journal	Organometallics
Volume	20
Issue number	6
DOIs	https://doi.org/10.1021/om000909q
Publication status	Published - Mar 19 2001
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om000909q

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title = "Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene",

abstract = "The reactions of pure cis- and trans-3,4-benzo-1,2-di(tert-butyl)-1, 2-dimethyl-1,2-disilacyclobut-3-ene (1a and 1b) with oxygen in the presence of AIBN proceeded stereospecifically to give the respective siloxanes. The palladium-catalyzed reactions of 1a and 1b with phenylacetylene and 1-hexyne produced stereospecifically cis- and trans-5,6-benzo-1,4-disilacyclohexa-2,5-dienes.",

author = "Mitsuo Ishikawa and Junnai Ikadai and Akinobu Naka and Joji Ohshita and Atsutaka Kunai and Kazunari Yoshizawa and Kang, \{Song Yun\} and Tokio Yamabe",

year = "2001",

month = mar,

day = "19",

doi = "10.1021/om000909q",

language = "English",

volume = "20",

pages = "1059--1061",

journal = "Organometallics",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene

AU - Ishikawa, Mitsuo

AU - Ikadai, Junnai

AU - Naka, Akinobu

AU - Ohshita, Joji

AU - Kunai, Atsutaka

AU - Yoshizawa, Kazunari

AU - Kang, Song Yun

AU - Yamabe, Tokio

PY - 2001/3/19

Y1 - 2001/3/19

N2 - The reactions of pure cis- and trans-3,4-benzo-1,2-di(tert-butyl)-1, 2-dimethyl-1,2-disilacyclobut-3-ene (1a and 1b) with oxygen in the presence of AIBN proceeded stereospecifically to give the respective siloxanes. The palladium-catalyzed reactions of 1a and 1b with phenylacetylene and 1-hexyne produced stereospecifically cis- and trans-5,6-benzo-1,4-disilacyclohexa-2,5-dienes.

AB - The reactions of pure cis- and trans-3,4-benzo-1,2-di(tert-butyl)-1, 2-dimethyl-1,2-disilacyclobut-3-ene (1a and 1b) with oxygen in the presence of AIBN proceeded stereospecifically to give the respective siloxanes. The palladium-catalyzed reactions of 1a and 1b with phenylacetylene and 1-hexyne produced stereospecifically cis- and trans-5,6-benzo-1,4-disilacyclohexa-2,5-dienes.

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DO - 10.1021/om000909q

M3 - Article

AN - SCOPUS:0035911990

SN - 0276-7333

VL - 20

SP - 1059

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JO - Organometallics

JF - Organometallics

IS - 6

ER -

Synthesis and stereochemistry of cis- and trans-3,4-benzo-1,2-di(tert- butyl)-1,2-dimethyl-1,2-disilacyclobutene

Abstract

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