Synthesis and redox behavior of Wurster blue cyclophanes

Hiroyuki Takemura; Kô Takehara; Masafumi Ata

doi:10.1002/ejoc.200400289

Synthesis and redox behavior of Wurster blue cyclophanes

Hiroyuki Takemura, Kô Takehara, Masafumi Ata

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Two cyclophanes composed of two p-phenylenediamine (PPD) units connected by methylene chains of different lengths (1c, n = 3; 2c, n = 5) have been synthesized. The PPD unit of cyclophane 1c was oxidized by a two-electron transfer process to give 1c²⁺ at the first oxidation potential. In contrast, 2c was oxidized by a one-electron transfer process to give 2c ⁺ and then 2c²⁺.

Original language	English
Pages (from-to)	4936-4941
Number of pages	6
Journal	European Journal of Organic Chemistry
Issue number	23
DOIs	https://doi.org/10.1002/ejoc.200400289
Publication status	Published - Nov 26 2004

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry

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AU - Takehara, Kô

AU - Ata, Masafumi

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Synthesis and redox behavior of Wurster blue cyclophanes

Abstract

All Science Journal Classification (ASJC) codes

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